Multicomponent-Reaction-Ready Biomass-Sourced Organic Hybrids Fabricated via the Surface Immobilization of Polymers with Lignin-Based Compounds

Takashi Hamada*, Shuhei Yamashita, Masaaki Omichi, Kimio Yoshimura, Yuji Ueki, Noriaki Seko, Ryohei Kakuchi

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

12 Citations (Scopus)

Abstract

Compounds derived from two major biomass components, cellulose and lignin, were artificially recombined via the radiation-induced graft polymerization of vinyl monomers, which could be potentially sourced from lignin, onto cellulose fabric. This process yielded organic hybrids featuring a cellulose substrate and surface aldehyde groups from lignin-obtained vanillin. Then, the surface Kabachnik-Fields three-component reaction (KF-3CR) of poly(methacrylated vanillin) (PMV)-sourced aldehydes was carried out with amines and phosphites. Overall, the surface KF-3CR on the cellulose fabric grafted with PMV represents a facile preparation of multifunctional molecules on cellulose surfaces along with α-amino phosphonate ester integrations.

Original languageEnglish
Pages (from-to)7795-7803
Number of pages9
JournalACS Sustainable Chemistry and Engineering
Volume7
Issue number8
DOIs
Publication statusPublished - 2019 Apr 15
Externally publishedYes

Keywords

  • Amino phosphonates
  • Cellulose
  • Lignin-sourced
  • Multicomponent reactions
  • Organic hybrids

ASJC Scopus subject areas

  • Chemistry(all)
  • Environmental Chemistry
  • Chemical Engineering(all)
  • Renewable Energy, Sustainability and the Environment

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