Multinuclear catalyst for copper-catalyzed asymmetric conjugate addition of organozinc reagents

Kohei Endo; Mika Ogawa; Takanori Shibata

doi:10.1002/anie.200906839

Multinuclear catalyst for copper-catalyzed asymmetric conjugate addition of organozinc reagents

Kohei Endo^*, Mika Ogawa, Takanori Shibata

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

68 Citations (Scopus)

Abstract

(Figure Presented) A whole lot o' metal: An efficient copper-catalyzed asymmetric conjugate addition was achieved using a binol-derived ligand. The catalytic system has a turnover number of 2000, and the excellent cata-lytic performance could be attributed to the generation of a multinuclear complex such as 1. binol = 2, 2'-dihydroxy-l, 1'-binaphthyl.

Original language	English
Pages (from-to)	2410-2413
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	13
DOIs	https://doi.org/10.1002/anie.200906839
Publication status	Published - 2010 Mar 22

Keywords

Alkylation
Copper
Michael addition
Synthetic methods
Zinc

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.200906839

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title = "Multinuclear catalyst for copper-catalyzed asymmetric conjugate addition of organozinc reagents",

abstract = "(Figure Presented) A whole lot o' metal: An efficient copper-catalyzed asymmetric conjugate addition was achieved using a binol-derived ligand. The catalytic system has a turnover number of 2000, and the excellent cata-lytic performance could be attributed to the generation of a multinuclear complex such as 1. binol = 2, 2'-dihydroxy-l, 1'-binaphthyl.",

keywords = "Alkylation, Copper, Michael addition, Synthetic methods, Zinc",

author = "Kohei Endo and Mika Ogawa and Takanori Shibata",

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T1 - Multinuclear catalyst for copper-catalyzed asymmetric conjugate addition of organozinc reagents

AU - Endo, Kohei

AU - Ogawa, Mika

AU - Shibata, Takanori

PY - 2010/3/22

Y1 - 2010/3/22

N2 - (Figure Presented) A whole lot o' metal: An efficient copper-catalyzed asymmetric conjugate addition was achieved using a binol-derived ligand. The catalytic system has a turnover number of 2000, and the excellent cata-lytic performance could be attributed to the generation of a multinuclear complex such as 1. binol = 2, 2'-dihydroxy-l, 1'-binaphthyl.

AB - (Figure Presented) A whole lot o' metal: An efficient copper-catalyzed asymmetric conjugate addition was achieved using a binol-derived ligand. The catalytic system has a turnover number of 2000, and the excellent cata-lytic performance could be attributed to the generation of a multinuclear complex such as 1. binol = 2, 2'-dihydroxy-l, 1'-binaphthyl.

KW - Alkylation

KW - Copper

KW - Michael addition

KW - Synthetic methods

KW - Zinc

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U2 - 10.1002/anie.200906839

DO - 10.1002/anie.200906839

M3 - Article

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 13

ER -

Multinuclear catalyst for copper-catalyzed asymmetric conjugate addition of organozinc reagents

Abstract

Keywords

ASJC Scopus subject areas

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