Multinuclear catalyst for copper-catalyzed asymmetric conjugate addition of organozinc reagents

Kohei Endo, Mika Ogawa, Takanori Shibata

Research output: Contribution to journalArticle

63 Citations (Scopus)

Abstract

(Figure Presented) A whole lot o' metal: An efficient copper-catalyzed asymmetric conjugate addition was achieved using a binol-derived ligand. The catalytic system has a turnover number of 2000, and the excellent cata-lytic performance could be attributed to the generation of a multinuclear complex such as 1. binol = 2, 2'-dihydroxy-l, 1'-binaphthyl.

Original languageEnglish
Pages (from-to)2410-2413
Number of pages4
JournalAngewandte Chemie - International Edition
Volume49
Issue number13
DOIs
Publication statusPublished - 2010 Mar 22

Keywords

  • Alkylation
  • Copper
  • Michael addition
  • Synthetic methods
  • Zinc

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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