Nano-donuts from pH-dependent block restructuring in amphiphilic ABA triblock copolymer vesicles at the air-water interface

Jin Young Park, Ming Liu, Jimmy Mays, Mark Dadmun, Rigoberto Advincula

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

To understand the nature of polymers capable of forming multiply bound polymer chains (MBPCs) on surfaces, the Langmuir-Blodgett (LB) technique and Scanning Probe Microscopy (SPM) have been utilized to investigate surface morphology of the amphiphilic triblock copolymer (P2VP-b-dPS-b-P2VP, M n = 125,000, dPS:P2VP = 1:1) at the air-water interface. The LB monolayer studies were carried out via π-A isotherms, compression-expansion cycles, kinetic stability, and nanoscopic surface morphological behavior. A strong pH effect was observed on the surface limiting area, stability, and morphology forming various 2-D aggregates. In particular, well-ordered interesting nanostructures (nano-donut formation) of the triblock copolymer aggregates depend on the effect of pH on the hydrophilic P2VP blocks, acting as a "cushion" at the air-water interface. In addition, equilibrium factors between the adsorption of the hydrophilic outer blocks (related to its solubility) and the entanglement of the hydrophobic dPS blocks during the evaporation of the spreading solution may play a critical role.

Original languageEnglish
Pages (from-to)747-749
Number of pages3
JournalSoft Matter
Volume5
Issue number4
DOIs
Publication statusPublished - 2009
Externally publishedYes

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Block copolymers
copolymers
Water
air
Polymers
Air
pH effects
water
Scanning probe microscopy
cushions
Surface morphology
Isotherms
Monolayers
Nanostructures
polymers
Evaporation
Solubility
Adsorption
isotherms
Kinetics

ASJC Scopus subject areas

  • Chemistry(all)
  • Condensed Matter Physics

Cite this

Nano-donuts from pH-dependent block restructuring in amphiphilic ABA triblock copolymer vesicles at the air-water interface. / Park, Jin Young; Liu, Ming; Mays, Jimmy; Dadmun, Mark; Advincula, Rigoberto.

In: Soft Matter, Vol. 5, No. 4, 2009, p. 747-749.

Research output: Contribution to journalArticle

Park, Jin Young ; Liu, Ming ; Mays, Jimmy ; Dadmun, Mark ; Advincula, Rigoberto. / Nano-donuts from pH-dependent block restructuring in amphiphilic ABA triblock copolymer vesicles at the air-water interface. In: Soft Matter. 2009 ; Vol. 5, No. 4. pp. 747-749.
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