Negative thermoelectric power induced by positive carriers in CaMn 3-xCuxMn4O12

Wataru Kobayashi; Ichiro Terasaki; Masashi Mikami; Ryoji Funahashi

doi:10.1143/JPSJ.73.523

Negative thermoelectric power induced by positive carriers in CaMn 3-xCuxMn4O12

Wataru Kobayashi^*, Ichiro Terasaki, Masashi Mikami, Ryoji Funahashi

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

We have found that the thermoelectric power of the ordered perovskite CaMn_3-xCu_xMn₄O₁₂ is negative at high temperature (-35 μV/K at 1000 K), although this material is a hole-doped conductor in which Cu²⁺ is substituted for Mn³⁺. This is quantitatively explained by the extended Heikes formula, where entropy flows in a direction opposite to the charge.

Original language	English
Pages (from-to)	523-525
Number of pages	3
Journal	Journal of the Physical Society of Japan
Volume	73
Issue number	3
DOIs	https://doi.org/10.1143/JPSJ.73.523
Publication status	Published - 2004 Mar

Keywords

Heikes formula
Spin and orbital degeneracy
Thermoelectric power
Transition-metal oxide

ASJC Scopus subject areas

Physics and Astronomy(all)

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10.1143/JPSJ.73.523

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title = "Negative thermoelectric power induced by positive carriers in CaMn 3-xCuxMn4O12 ",

abstract = "We have found that the thermoelectric power of the ordered perovskite CaMn3-xCuxMn4O12 is negative at high temperature (-35 μV/K at 1000 K), although this material is a hole-doped conductor in which Cu2+ is substituted for Mn3+. This is quantitatively explained by the extended Heikes formula, where entropy flows in a direction opposite to the charge.",

keywords = "Heikes formula, Spin and orbital degeneracy, Thermoelectric power, Transition-metal oxide",

author = "Wataru Kobayashi and Ichiro Terasaki and Masashi Mikami and Ryoji Funahashi",

year = "2004",

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doi = "10.1143/JPSJ.73.523",

language = "English",

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T1 - Negative thermoelectric power induced by positive carriers in CaMn 3-xCuxMn4O12

AU - Kobayashi, Wataru

AU - Terasaki, Ichiro

AU - Mikami, Masashi

AU - Funahashi, Ryoji

PY - 2004/3

Y1 - 2004/3

N2 - We have found that the thermoelectric power of the ordered perovskite CaMn3-xCuxMn4O12 is negative at high temperature (-35 μV/K at 1000 K), although this material is a hole-doped conductor in which Cu2+ is substituted for Mn3+. This is quantitatively explained by the extended Heikes formula, where entropy flows in a direction opposite to the charge.

AB - We have found that the thermoelectric power of the ordered perovskite CaMn3-xCuxMn4O12 is negative at high temperature (-35 μV/K at 1000 K), although this material is a hole-doped conductor in which Cu2+ is substituted for Mn3+. This is quantitatively explained by the extended Heikes formula, where entropy flows in a direction opposite to the charge.

KW - Heikes formula

KW - Spin and orbital degeneracy

KW - Thermoelectric power

KW - Transition-metal oxide

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JO - Journal of the Physical Society of Japan

JF - Journal of the Physical Society of Japan

SN - 0031-9015

IS - 3

ER -

Negative thermoelectric power induced by positive carriers in CaMn 3-xCuxMn4O12

Abstract

Keywords

ASJC Scopus subject areas

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