New construction of the bicyclo[3.3.1]nonane system via Lewis acid promoted regioselective ring-opening reaction of the tricyclo[4.4.0.05,7]dec-2-ene derivative

Masahito Abe, Masahisa Nakada

    Research output: Contribution to journalArticle

    25 Citations (Scopus)

    Abstract

    A new access to the bicyclo[3.3.1]nonane system, which is a common structure in a number of polyisoprenylated phloroglucinol derivatives (phloroglucins), has been developed via the Lewis acid promoted regioselective ring-opening reaction of the cyclopropane, a tricyclo[4.4.0.05,7]dec-2-ene derivative.

    Original languageEnglish
    Pages (from-to)6347-6351
    Number of pages5
    JournalTetrahedron Letters
    Volume47
    Issue number36
    DOIs
    Publication statusPublished - 2006 Sep 4

    Fingerprint

    Phloroglucinol
    Lewis Acids
    Derivatives
    cyclopropane
    bicyclo(3.3.1)nonane

    ASJC Scopus subject areas

    • Biochemistry
    • Organic Chemistry
    • Drug Discovery

    Cite this

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    abstract = "A new access to the bicyclo[3.3.1]nonane system, which is a common structure in a number of polyisoprenylated phloroglucinol derivatives (phloroglucins), has been developed via the Lewis acid promoted regioselective ring-opening reaction of the cyclopropane, a tricyclo[4.4.0.05,7]dec-2-ene derivative.",
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    AU - Nakada, Masahisa

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    N2 - A new access to the bicyclo[3.3.1]nonane system, which is a common structure in a number of polyisoprenylated phloroglucinol derivatives (phloroglucins), has been developed via the Lewis acid promoted regioselective ring-opening reaction of the cyclopropane, a tricyclo[4.4.0.05,7]dec-2-ene derivative.

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