New light-emitting poly{(9,9-di-n-octylfluorenediyl vinylene)-alt-[1,5-(2,6-dioctyloxy)naphthalene vinylene]}

Piched Anuragudom; Jad El-daye; Pawilai Chinwangso; Rigoberto C. Advincula; Sukon Phanichphant; T. Randall Lee

doi:10.1002/pi.2999

New light-emitting poly{(9,9-di-n-octylfluorenediyl vinylene)-alt-[1,5-(2,6-dioctyloxy)naphthalene vinylene]}

Piched Anuragudom^*, Jad El-daye, Pawilai Chinwangso, Rigoberto C. Advincula, Sukon Phanichphant, T. Randall Lee

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

A new conjugated light-emitting AB copolymer containing alternating fluorene and naphthalene units, poly{(9,9-di-n-octylfluorenediyl vinylene)-alt-[1,5-(2,6-dioctyloxy)naphthalene vinylene]} (PFV-alt-PNV), was synthesized via Horner-Emmons polymerization. The polymer is completely soluble in common organic solvents and exhibits good thermal stability up to 400 °C. UV-visible, fluorescence and photoluminescence measurements of the copolymer show peak maxima at 427, 500 and 526 nm, respectively. A light-emitting device containing the new polymer was fabricated using a simple indium tin oxide configuration: (ITO)/PEDOT:PSS/PFV-alt-PNV/Al. Measurements of current versus electric field were carried out, with an onset of light emission occurring at 2.5 V. The electroluminescence brightness was observed to reach a maximum of 5000 cd m^-2.

Original language	English
Pages (from-to)	660-665
Number of pages	6
Journal	Polymer International
Volume	60
Issue number	4
DOIs	https://doi.org/10.1002/pi.2999
Publication status	Published - 2011 Apr
Externally published	Yes

Keywords

Horner-Emmons polymerization
Light-emitting polymer
Poly{(9,9-di-n-octylfluorenediyl vinylene)-alt-[1,5-(2,6-dioctyloxy)naphthalene vinylene]} (PFV-alt-PNV)

ASJC Scopus subject areas

Polymers and Plastics

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10.1002/pi.2999

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@article{a3a175f7bdea40c78ebb6e6172596cd9,

title = "New light-emitting poly{(9,9-di-n-octylfluorenediyl vinylene)-alt-[1,5-(2,6-dioctyloxy)naphthalene vinylene]}",

abstract = "A new conjugated light-emitting AB copolymer containing alternating fluorene and naphthalene units, poly{(9,9-di-n-octylfluorenediyl vinylene)-alt-[1,5-(2,6-dioctyloxy)naphthalene vinylene]} (PFV-alt-PNV), was synthesized via Horner-Emmons polymerization. The polymer is completely soluble in common organic solvents and exhibits good thermal stability up to 400 °C. UV-visible, fluorescence and photoluminescence measurements of the copolymer show peak maxima at 427, 500 and 526 nm, respectively. A light-emitting device containing the new polymer was fabricated using a simple indium tin oxide configuration: (ITO)/PEDOT:PSS/PFV-alt-PNV/Al. Measurements of current versus electric field were carried out, with an onset of light emission occurring at 2.5 V. The electroluminescence brightness was observed to reach a maximum of 5000 cd m-2.",

keywords = "Horner-Emmons polymerization, Light-emitting polymer, Poly{(9,9-di-n-octylfluorenediyl vinylene)-alt-[1,5-(2,6-dioctyloxy)naphthalene vinylene]} (PFV-alt-PNV)",

author = "Piched Anuragudom and Jad El-daye and Pawilai Chinwangso and Advincula, {Rigoberto C.} and Sukon Phanichphant and Lee, {T. Randall}",

year = "2011",

month = apr,

doi = "10.1002/pi.2999",

language = "English",

volume = "60",

pages = "660--665",

journal = "British Polymer Journal",

issn = "0959-8103",

publisher = "John Wiley and Sons Ltd",

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TY - JOUR

T1 - New light-emitting poly{(9,9-di-n-octylfluorenediyl vinylene)-alt-[1,5-(2,6-dioctyloxy)naphthalene vinylene]}

AU - Anuragudom, Piched

AU - El-daye, Jad

AU - Chinwangso, Pawilai

AU - Advincula, Rigoberto C.

AU - Phanichphant, Sukon

AU - Lee, T. Randall

PY - 2011/4

Y1 - 2011/4

N2 - A new conjugated light-emitting AB copolymer containing alternating fluorene and naphthalene units, poly{(9,9-di-n-octylfluorenediyl vinylene)-alt-[1,5-(2,6-dioctyloxy)naphthalene vinylene]} (PFV-alt-PNV), was synthesized via Horner-Emmons polymerization. The polymer is completely soluble in common organic solvents and exhibits good thermal stability up to 400 °C. UV-visible, fluorescence and photoluminescence measurements of the copolymer show peak maxima at 427, 500 and 526 nm, respectively. A light-emitting device containing the new polymer was fabricated using a simple indium tin oxide configuration: (ITO)/PEDOT:PSS/PFV-alt-PNV/Al. Measurements of current versus electric field were carried out, with an onset of light emission occurring at 2.5 V. The electroluminescence brightness was observed to reach a maximum of 5000 cd m-2.

AB - A new conjugated light-emitting AB copolymer containing alternating fluorene and naphthalene units, poly{(9,9-di-n-octylfluorenediyl vinylene)-alt-[1,5-(2,6-dioctyloxy)naphthalene vinylene]} (PFV-alt-PNV), was synthesized via Horner-Emmons polymerization. The polymer is completely soluble in common organic solvents and exhibits good thermal stability up to 400 °C. UV-visible, fluorescence and photoluminescence measurements of the copolymer show peak maxima at 427, 500 and 526 nm, respectively. A light-emitting device containing the new polymer was fabricated using a simple indium tin oxide configuration: (ITO)/PEDOT:PSS/PFV-alt-PNV/Al. Measurements of current versus electric field were carried out, with an onset of light emission occurring at 2.5 V. The electroluminescence brightness was observed to reach a maximum of 5000 cd m-2.

KW - Horner-Emmons polymerization

KW - Light-emitting polymer

KW - Poly{(9,9-di-n-octylfluorenediyl vinylene)-alt-[1,5-(2,6-dioctyloxy)naphthalene vinylene]} (PFV-alt-PNV)

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New light-emitting poly{(9,9-di-n-octylfluorenediyl vinylene)-alt-[1,5-(2,6-dioctyloxy)naphthalene vinylene]}

Abstract

Keywords

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