New synthesis of polyaromatics through oxidative polymerization by using metal complexes with air

Eishun Tsuchida; Kimihisa Yamamoto; Hiroyuki Nishide

doi:10.1002/masy.19920590103

New synthesis of polyaromatics through oxidative polymerization by using metal complexes with air

Eishun Tsuchida, Kimihisa Yamamoto, Hiroyuki Nishide

Waseda Research Institute for Science and Engineering

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The oxidative polymerization provides a new synthetic route to polyaromatics. Poly(p‐phenylene sulfide) (PPS) is produced by oxidative polymerization of thiophenol with a vanadyl complex catalyst. The metal complexes act as an efficient catalyst of oxygen oxidative polymerization. The polymerization to yield PPS is discussed especially focusing on the catalytic mechanism of the complexes.

Original language	English
Pages (from-to)	1-16
Number of pages	16
Journal	Macromolecular Symposia
Volume	59
Issue number	1
DOIs	https://doi.org/10.1002/masy.19920590103
Publication status	Published - 1992

ASJC Scopus subject areas

Condensed Matter Physics
Organic Chemistry
Polymers and Plastics
Materials Chemistry

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abstract = "The oxidative polymerization provides a new synthetic route to polyaromatics. Poly(p‐phenylene sulfide) (PPS) is produced by oxidative polymerization of thiophenol with a vanadyl complex catalyst. The metal complexes act as an efficient catalyst of oxygen oxidative polymerization. The polymerization to yield PPS is discussed especially focusing on the catalytic mechanism of the complexes.",

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