New synthesis of poly(phenylene sulfide)s through O2 oxidative polymerization of diphenyl disulfide with VO catalyst

Eishun Tsuchida; Kimihisa Yamamoto; Mitsutoshi Jikei; Hiroyuki Nishide

New synthesis of poly(phenylene sulfide)s through O₂ oxidative polymerization of diphenyl disulfide with VO catalyst

Eishun Tsuchida, Kimihisa Yamamoto, Mitsutoshi Jikei, Hiroyuki Nishide

Waseda Research Institute for Science and Engineering

Research output: Contribution to journal › Article › peer-review

40 Citations (Scopus)

Abstract

This communication describes a novel and convenient synthetic route to poly(phenylene sulfide)s (Scheme I). Diphenyl disulfide is polymerized to PPS with high purity in high yield, in the presence of a catalytic amount of vanadyl acetylacetonate (VO(acac)₂) under an air atmosphere at room temperature. It is shown that oxygen is essential for the polymerization of diphenyl disulfide. In the presence of VO(acac)₂, the polymerization is accompanied with a quantitative oxygen uptake. More oxygen uptake was observed whenever additional diphenyl disulfide was added to the reaction mixture.

Original language	English
Pages (from-to)	4138-4140
Number of pages	3
Journal	Macromolecules
Volume	22
Issue number	10
Publication status	Published - 1989 Oct

ASJC Scopus subject areas

Materials Chemistry

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abstract = "This communication describes a novel and convenient synthetic route to poly(phenylene sulfide)s (Scheme I). Diphenyl disulfide is polymerized to PPS with high purity in high yield, in the presence of a catalytic amount of vanadyl acetylacetonate (VO(acac)2) under an air atmosphere at room temperature. It is shown that oxygen is essential for the polymerization of diphenyl disulfide. In the presence of VO(acac)2, the polymerization is accompanied with a quantitative oxygen uptake. More oxygen uptake was observed whenever additional diphenyl disulfide was added to the reaction mixture.",

author = "Eishun Tsuchida and Kimihisa Yamamoto and Mitsutoshi Jikei and Hiroyuki Nishide",

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AU - Tsuchida, Eishun

AU - Yamamoto, Kimihisa

AU - Jikei, Mitsutoshi

AU - Nishide, Hiroyuki

PY - 1989/10

Y1 - 1989/10

N2 - This communication describes a novel and convenient synthetic route to poly(phenylene sulfide)s (Scheme I). Diphenyl disulfide is polymerized to PPS with high purity in high yield, in the presence of a catalytic amount of vanadyl acetylacetonate (VO(acac)2) under an air atmosphere at room temperature. It is shown that oxygen is essential for the polymerization of diphenyl disulfide. In the presence of VO(acac)2, the polymerization is accompanied with a quantitative oxygen uptake. More oxygen uptake was observed whenever additional diphenyl disulfide was added to the reaction mixture.

AB - This communication describes a novel and convenient synthetic route to poly(phenylene sulfide)s (Scheme I). Diphenyl disulfide is polymerized to PPS with high purity in high yield, in the presence of a catalytic amount of vanadyl acetylacetonate (VO(acac)2) under an air atmosphere at room temperature. It is shown that oxygen is essential for the polymerization of diphenyl disulfide. In the presence of VO(acac)2, the polymerization is accompanied with a quantitative oxygen uptake. More oxygen uptake was observed whenever additional diphenyl disulfide was added to the reaction mixture.

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SN - 0024-9297

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New synthesis of poly(phenylene sulfide)s through O2 oxidative polymerization of diphenyl disulfide with VO catalyst

Abstract

ASJC Scopus subject areas

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New synthesis of poly(phenylene sulfide)s through O₂ oxidative polymerization of diphenyl disulfide with VO catalyst