Nitroxide polymer networks formed by Michael addition: On site-cured electrode-active organic coating

Takeshi Ibe; Rainer B. Frings; Artur Lachowicz; Soichi Kyo; Hiroyuki Nishide

doi:10.1039/c002797a

Nitroxide polymer networks formed by Michael addition: On site-cured electrode-active organic coating

Takeshi Ibe, Rainer B. Frings, Artur Lachowicz, Soichi Kyo, Hiroyuki Nishide^*

^*Corresponding author for this work

Waseda Research Institute for Science and Engineering

Research output: Contribution to journal › Article › peer-review

51 Citations (Scopus)

Abstract

Highly and homogeneously crosslinked poly(β-ketoester) networks densely bearing robust nitroxide radicals were prepared via a click-type and stepwise Michael polyaddition. A half-battery cell composed of the thermally-cured radical network coatings displayed a rapid, reversible, and almost stoichiometric redox-activity even with a thickness of ca. 10 μm, which may be applicable as the electrode of organic-based rechargeable devices.

Original language	English
Pages (from-to)	3475-3477
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	20
DOIs	https://doi.org/10.1039/c002797a
Publication status	Published - 2010

ASJC Scopus subject areas

Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Catalysis
Chemistry(all)

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10.1039/c002797a

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abstract = "Highly and homogeneously crosslinked poly(β-ketoester) networks densely bearing robust nitroxide radicals were prepared via a click-type and stepwise Michael polyaddition. A half-battery cell composed of the thermally-cured radical network coatings displayed a rapid, reversible, and almost stoichiometric redox-activity even with a thickness of ca. 10 μm, which may be applicable as the electrode of organic-based rechargeable devices.",

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AU - Ibe, Takeshi

AU - Frings, Rainer B.

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AU - Kyo, Soichi

AU - Nishide, Hiroyuki

PY - 2010

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AB - Highly and homogeneously crosslinked poly(β-ketoester) networks densely bearing robust nitroxide radicals were prepared via a click-type and stepwise Michael polyaddition. A half-battery cell composed of the thermally-cured radical network coatings displayed a rapid, reversible, and almost stoichiometric redox-activity even with a thickness of ca. 10 μm, which may be applicable as the electrode of organic-based rechargeable devices.

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Nitroxide polymer networks formed by Michael addition: On site-cured electrode-active organic coating

Abstract

ASJC Scopus subject areas

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