Nitroxide polymer networks formed by Michael addition

On site-cured electrode-active organic coating

Takeshi Ibe, Rainer B. Frings, Artur Lachowicz, Soichi Kyo, Hiroyuki Nishide

Research output: Contribution to journalArticle

36 Citations (Scopus)

Abstract

Highly and homogeneously crosslinked poly(β-ketoester) networks densely bearing robust nitroxide radicals were prepared via a click-type and stepwise Michael polyaddition. A half-battery cell composed of the thermally-cured radical network coatings displayed a rapid, reversible, and almost stoichiometric redox-activity even with a thickness of ca. 10 μm, which may be applicable as the electrode of organic-based rechargeable devices.

Original languageEnglish
Pages (from-to)3475-3477
Number of pages3
JournalChemical Communications
Volume46
Issue number20
DOIs
Publication statusPublished - 2010

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Bearings (structural)
Organic coatings
Polymers
Coatings
Electrodes
Oxidation-Reduction
nitroxyl

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

Nitroxide polymer networks formed by Michael addition : On site-cured electrode-active organic coating. / Ibe, Takeshi; Frings, Rainer B.; Lachowicz, Artur; Kyo, Soichi; Nishide, Hiroyuki.

In: Chemical Communications, Vol. 46, No. 20, 2010, p. 3475-3477.

Research output: Contribution to journalArticle

Ibe, Takeshi ; Frings, Rainer B. ; Lachowicz, Artur ; Kyo, Soichi ; Nishide, Hiroyuki. / Nitroxide polymer networks formed by Michael addition : On site-cured electrode-active organic coating. In: Chemical Communications. 2010 ; Vol. 46, No. 20. pp. 3475-3477.
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