Abstract
Highly and homogeneously crosslinked poly(β-ketoester) networks densely bearing robust nitroxide radicals were prepared via a click-type and stepwise Michael polyaddition. A half-battery cell composed of the thermally-cured radical network coatings displayed a rapid, reversible, and almost stoichiometric redox-activity even with a thickness of ca. 10 μm, which may be applicable as the electrode of organic-based rechargeable devices.
| Original language | English |
|---|---|
| Pages (from-to) | 3475-3477 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Volume | 46 |
| Issue number | 20 |
| DOIs | |
| Publication status | Published - 2010 |
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ASJC Scopus subject areas
- Metals and Alloys
- Materials Chemistry
- Surfaces, Coatings and Films
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Catalysis
- Chemistry(all)
Cite this
Nitroxide polymer networks formed by Michael addition : On site-cured electrode-active organic coating. / Ibe, Takeshi; Frings, Rainer B.; Lachowicz, Artur; Kyo, Soichi; Nishide, Hiroyuki.
In: Chemical Communications, Vol. 46, No. 20, 2010, p. 3475-3477.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Nitroxide polymer networks formed by Michael addition
T2 - On site-cured electrode-active organic coating
AU - Ibe, Takeshi
AU - Frings, Rainer B.
AU - Lachowicz, Artur
AU - Kyo, Soichi
AU - Nishide, Hiroyuki
PY - 2010
Y1 - 2010
N2 - Highly and homogeneously crosslinked poly(β-ketoester) networks densely bearing robust nitroxide radicals were prepared via a click-type and stepwise Michael polyaddition. A half-battery cell composed of the thermally-cured radical network coatings displayed a rapid, reversible, and almost stoichiometric redox-activity even with a thickness of ca. 10 μm, which may be applicable as the electrode of organic-based rechargeable devices.
AB - Highly and homogeneously crosslinked poly(β-ketoester) networks densely bearing robust nitroxide radicals were prepared via a click-type and stepwise Michael polyaddition. A half-battery cell composed of the thermally-cured radical network coatings displayed a rapid, reversible, and almost stoichiometric redox-activity even with a thickness of ca. 10 μm, which may be applicable as the electrode of organic-based rechargeable devices.
UR - http://www.scopus.com/inward/record.url?scp=77952377152&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=77952377152&partnerID=8YFLogxK
U2 - 10.1039/c002797a
DO - 10.1039/c002797a
M3 - Article
VL - 46
SP - 3475
EP - 3477
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 20
ER -