Nitroxide polymer networks formed by Michael addition: On site-cured electrode-active organic coating

Takeshi Ibe, Rainer B. Frings, Artur Lachowicz, Soichi Kyo, Hiroyuki Nishide

Research output: Contribution to journalArticle

39 Citations (Scopus)

Abstract

Highly and homogeneously crosslinked poly(β-ketoester) networks densely bearing robust nitroxide radicals were prepared via a click-type and stepwise Michael polyaddition. A half-battery cell composed of the thermally-cured radical network coatings displayed a rapid, reversible, and almost stoichiometric redox-activity even with a thickness of ca. 10 μm, which may be applicable as the electrode of organic-based rechargeable devices.

Original languageEnglish
Pages (from-to)3475-3477
Number of pages3
JournalChemical Communications
Volume46
Issue number20
DOIs
Publication statusPublished - 2010

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

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