Nitroxide polymer networks formed by Michael addition: On site-cured electrode-active organic coating

Takeshi Ibe; Rainer B. Frings; Artur Lachowicz; Soichi Kyo; Hiroyuki Nishide

doi:10.1039/c002797a

Nitroxide polymer networks formed by Michael addition: On site-cured electrode-active organic coating

Takeshi Ibe, Rainer B. Frings, Artur Lachowicz, Soichi Kyo, Hiroyuki Nishide

Waseda Research Institute for Science and Engineering

Research output: Contribution to journal › Article

38 Citations (Scopus)

Abstract

Highly and homogeneously crosslinked poly(β-ketoester) networks densely bearing robust nitroxide radicals were prepared via a click-type and stepwise Michael polyaddition. A half-battery cell composed of the thermally-cured radical network coatings displayed a rapid, reversible, and almost stoichiometric redox-activity even with a thickness of ca. 10 μm, which may be applicable as the electrode of organic-based rechargeable devices.

Original language	English
Pages (from-to)	3475-3477
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	20
DOIs	https://doi.org/10.1039/c002797a
Publication status	Published - 2010

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ASJC Scopus subject areas

Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Catalysis
Chemistry(all)

Cite this

Ibe, T., Frings, R. B., Lachowicz, A., Kyo, S., & Nishide, H. (2010). Nitroxide polymer networks formed by Michael addition: On site-cured electrode-active organic coating. Chemical Communications, 46(20), 3475-3477. https://doi.org/10.1039/c002797a

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Access to Document

10.1039/c002797a