Nonlinear conductive spectra of ion-conducting polymers

Yoshiro Tajitsu, Yukihiko Ueno, Takeo Furukawa

Research output: Chapter in Book/Report/Conference proceedingConference contribution

2 Citations (Scopus)

Abstract

An ion-conducting polymer, tetraethylene oxide-organosiloxane (TEOS) copolymer, was synthesized and the linear and nonlinear complex conductivities were measured as a function of frequency. Observed spectra were reproduced by taking into account the interfacial and electrode polarizations. The most important findings are the very large dielectric relaxation strength and the very long hopping distance in noncrystalline ion-conducting polymers. The large relaxation strength suggests that the TEOS/Li- comprises an inhomogeneous system consisting of highly conductive and less conductive regions. It is speculated that such inhomogeneity governs the conduction mechanisms of the ionic conductor and results in a very long hopping distance. A combination of linear and nonlinear DC conductivities leads to a hopping distance of 200 nm.

Original languageEnglish
Title of host publicationProceedings - International Symposium on Electrets
Place of PublicationPiscataway, NJ, United States
PublisherPubl by IEEE
Pages165-170
Number of pages6
ISBN (Print)0780301129
Publication statusPublished - 1992 Jan
Externally publishedYes
Event7th International Symposium on Electrets - Berlin, Germ
Duration: 1991 Sep 251991 Sep 27

Other

Other7th International Symposium on Electrets
CityBerlin, Germ
Period91/9/2591/9/27

Fingerprint

Conducting polymers
Oxides
Dielectric relaxation
Ions
Copolymers
Polarization
Electrodes

ASJC Scopus subject areas

  • Electrical and Electronic Engineering

Cite this

Tajitsu, Y., Ueno, Y., & Furukawa, T. (1992). Nonlinear conductive spectra of ion-conducting polymers. In Proceedings - International Symposium on Electrets (pp. 165-170). Piscataway, NJ, United States: Publ by IEEE.

Nonlinear conductive spectra of ion-conducting polymers. / Tajitsu, Yoshiro; Ueno, Yukihiko; Furukawa, Takeo.

Proceedings - International Symposium on Electrets. Piscataway, NJ, United States : Publ by IEEE, 1992. p. 165-170.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Tajitsu, Y, Ueno, Y & Furukawa, T 1992, Nonlinear conductive spectra of ion-conducting polymers. in Proceedings - International Symposium on Electrets. Publ by IEEE, Piscataway, NJ, United States, pp. 165-170, 7th International Symposium on Electrets, Berlin, Germ, 91/9/25.
Tajitsu Y, Ueno Y, Furukawa T. Nonlinear conductive spectra of ion-conducting polymers. In Proceedings - International Symposium on Electrets. Piscataway, NJ, United States: Publ by IEEE. 1992. p. 165-170
Tajitsu, Yoshiro ; Ueno, Yukihiko ; Furukawa, Takeo. / Nonlinear conductive spectra of ion-conducting polymers. Proceedings - International Symposium on Electrets. Piscataway, NJ, United States : Publ by IEEE, 1992. pp. 165-170
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