Nonlinear Optical Property of Poly(Phenylenevinylene) Bearing π-Conjugated Radicals

Masahiro Takahashi; Shinji Yamada; Hiro Matsuda; Eishun Tsuchida; Hiroyuki Nishide

Nonlinear Optical Property of Poly(Phenylenevinylene) Bearing π-Conjugated Radicals

Masahiro Takahashi^*, Shinji Yamada, Hiro Matsuda, Eishun Tsuchida, Hiroyuki Nishide

^*Corresponding author for this work

Waseda Research Institute for Science and Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

The third order nonlinear optical susceptibility, χ⁽³⁾ of an open-shell and alternant polymer based on a π-conjugated polymer, poly(1,2-phenylenevinylene) bearing phenoxyl radicals at 4-position, was evaluated. The real and imaginary parts of χ⁽³⁾ of the poly (1,2-phenylenevinylene) derivative were enhanced three orders of magnitude at ca. 680 nm and reached ca. 10^-9 esu due to the phenoxyl radical formation.

Original language	English
Pages (from-to)	31-39
Number of pages	9
Journal	Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume	334
Publication status	Published - 1999

Keywords

π-conjugated polymer
Nonlinear optical susceptibility
Phenoxyl radical
Poly(phenylenevinylene)
Polyradical

ASJC Scopus subject areas

Condensed Matter Physics

Cite this

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title = "Nonlinear Optical Property of Poly(Phenylenevinylene) Bearing π-Conjugated Radicals",

abstract = "The third order nonlinear optical susceptibility, χ(3) of an open-shell and alternant polymer based on a π-conjugated polymer, poly(1,2-phenylenevinylene) bearing phenoxyl radicals at 4-position, was evaluated. The real and imaginary parts of χ(3) of the poly (1,2-phenylenevinylene) derivative were enhanced three orders of magnitude at ca. 680 nm and reached ca. 10-9 esu due to the phenoxyl radical formation.",

keywords = "π-conjugated polymer, Nonlinear optical susceptibility, Phenoxyl radical, Poly(phenylenevinylene), Polyradical",

author = "Masahiro Takahashi and Shinji Yamada and Hiro Matsuda and Eishun Tsuchida and Hiroyuki Nishide",

year = "1999",

language = "English",

volume = "334",

pages = "31--39",

journal = "Molecular Crystals and Liquid Crystals",

issn = "1542-1406",

publisher = "Taylor and Francis Ltd.",

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TY - JOUR

T1 - Nonlinear Optical Property of Poly(Phenylenevinylene) Bearing π-Conjugated Radicals

AU - Takahashi, Masahiro

AU - Yamada, Shinji

AU - Matsuda, Hiro

AU - Tsuchida, Eishun

AU - Nishide, Hiroyuki

PY - 1999

Y1 - 1999

N2 - The third order nonlinear optical susceptibility, χ(3) of an open-shell and alternant polymer based on a π-conjugated polymer, poly(1,2-phenylenevinylene) bearing phenoxyl radicals at 4-position, was evaluated. The real and imaginary parts of χ(3) of the poly (1,2-phenylenevinylene) derivative were enhanced three orders of magnitude at ca. 680 nm and reached ca. 10-9 esu due to the phenoxyl radical formation.

AB - The third order nonlinear optical susceptibility, χ(3) of an open-shell and alternant polymer based on a π-conjugated polymer, poly(1,2-phenylenevinylene) bearing phenoxyl radicals at 4-position, was evaluated. The real and imaginary parts of χ(3) of the poly (1,2-phenylenevinylene) derivative were enhanced three orders of magnitude at ca. 680 nm and reached ca. 10-9 esu due to the phenoxyl radical formation.

KW - π-conjugated polymer

KW - Nonlinear optical susceptibility

KW - Phenoxyl radical

KW - Poly(phenylenevinylene)

KW - Polyradical

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UR - http://www.scopus.com/inward/citedby.url?scp=0043228124&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0043228124

SN - 1542-1406

VL - 334

SP - 31

EP - 39

JO - Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals

ER -

Nonlinear Optical Property of Poly(Phenylenevinylene) Bearing π-Conjugated Radicals

Abstract

Keywords

ASJC Scopus subject areas

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