Novel electroactive polyelectrolyte with alternating seleno- and selenoniophenylene units

Kenji Miyatake; Tadahiro Ishikawa; Eishun Tsuchida

doi:10.1021/ma9902596

Novel electroactive polyelectrolyte with alternating seleno- and selenoniophenylene units

Kenji Miyatake, Tadahiro Ishikawa, Eishun Tsuchida

Graduate School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Poly(phenylselenonio-1,4-phenyleneseleno-1,4-phenylene triflate) containing selenoether and phenylselenonio groups was prepared by the polycondensation of diphenyl selenide and benzeneseleninic acid in triflic acid. The polymerization was also shown to proceed for diphenyl ether and diphenyl sulfide to give the corresponding poly (aryleneselenonium triflate)s. The polymer exhibited reversible redox waves at 0.70 V (vs Ag/AgCl) and semiconductivity of 5 × 10^-6S cm^-1 when doped with FeCl₃.

Original language	English
Pages (from-to)	4497-4499
Number of pages	3
Journal	Macromolecules
Volume	32
Issue number	13
DOIs	https://doi.org/10.1021/ma9902596
Publication status	Published - 1999 Jun 29

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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10.1021/ma9902596

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title = "Novel electroactive polyelectrolyte with alternating seleno- and selenoniophenylene units",

abstract = "Poly(phenylselenonio-1,4-phenyleneseleno-1,4-phenylene triflate) containing selenoether and phenylselenonio groups was prepared by the polycondensation of diphenyl selenide and benzeneseleninic acid in triflic acid. The polymerization was also shown to proceed for diphenyl ether and diphenyl sulfide to give the corresponding poly (aryleneselenonium triflate)s. The polymer exhibited reversible redox waves at 0.70 V (vs Ag/AgCl) and semiconductivity of 5 × 10-6S cm-1 when doped with FeCl3.",

author = "Kenji Miyatake and Tadahiro Ishikawa and Eishun Tsuchida",

year = "1999",

month = jun,

day = "29",

doi = "10.1021/ma9902596",

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T1 - Novel electroactive polyelectrolyte with alternating seleno- and selenoniophenylene units

AU - Miyatake, Kenji

AU - Ishikawa, Tadahiro

AU - Tsuchida, Eishun

PY - 1999/6/29

Y1 - 1999/6/29

N2 - Poly(phenylselenonio-1,4-phenyleneseleno-1,4-phenylene triflate) containing selenoether and phenylselenonio groups was prepared by the polycondensation of diphenyl selenide and benzeneseleninic acid in triflic acid. The polymerization was also shown to proceed for diphenyl ether and diphenyl sulfide to give the corresponding poly (aryleneselenonium triflate)s. The polymer exhibited reversible redox waves at 0.70 V (vs Ag/AgCl) and semiconductivity of 5 × 10-6S cm-1 when doped with FeCl3.

AB - Poly(phenylselenonio-1,4-phenyleneseleno-1,4-phenylene triflate) containing selenoether and phenylselenonio groups was prepared by the polycondensation of diphenyl selenide and benzeneseleninic acid in triflic acid. The polymerization was also shown to proceed for diphenyl ether and diphenyl sulfide to give the corresponding poly (aryleneselenonium triflate)s. The polymer exhibited reversible redox waves at 0.70 V (vs Ag/AgCl) and semiconductivity of 5 × 10-6S cm-1 when doped with FeCl3.

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U2 - 10.1021/ma9902596

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M3 - Article

AN - SCOPUS:0032638869

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JO - Macromolecules

JF - Macromolecules

IS - 13

ER -

Novel electroactive polyelectrolyte with alternating seleno- and selenoniophenylene units

Abstract

ASJC Scopus subject areas

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