Novel electrocatalysts for oxygen reduction using cobaltporphyrins that undergo facile electropolymerization

Makoto Yuasa, Kenichi Oyaizu, Aritomo Yamaguchi, Takuya Imai, Mizuki Kitao

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

[Meso-tetra (thiophen-3-yl)porphinato]cobalt (II) (CoT3ThP) complex, which undergoes facile electropolymerization, was synthesized by the dehydro-condensation reaction of pyrrole and 3-thienylaldehyde. The electroconductive thin film of CoT3ThP interconnected by 2,5-thienylene chains, was produced at the glassy carbon electrode by electrolysis. The catalytic activity for oxygen reduction at the modified electrode was evaluated by cyclic voltammetry. The catalytic current for the O2 reduction appeared near Ep = 0.2 V vs. SCE. It was found that the electrode modified with CoT3ThP film has a higher stability than that modified with porphyrin by absorption. Next, we chose carbon black with a high surface-area as a catalyst support, and CoT3ThP was electropolymerized under the condition of suspension of carbon black in an electrolyte solution. We found that the polymerized CoT3ThP was produced on the surface of the carbon nanoparticle. The carbon nanoparticles modified with polymerized CoT3ThP (polyCoT3ThP/C) were suspended in a Nafion solution, and a pseudo MEA (Membrane Electrode Assembly) was made by casting polyCoT3ThP/C on an edge-plane pyrolytic graphite electrode. The polyCoT3ThP/C catalyst was found to reduce O2 mainly with four electrons (the number of electrons transferred n=3.8) at a positive potential of Ep = 0.44 V vs. SCE. The catalytic activity of polyCoT3ThP/C was improved by heat treatment under an inert gas atmosphere (Ep = 0.47 V vs. SCE, n = 3.8). The results show the possibility of a novel cathode catalyst for use in fuel cells.

Original languageEnglish
Pages (from-to)182-188
Number of pages7
JournalKobunshi Ronbunshu
Volume63
Issue number3
DOIs
Publication statusPublished - 2006 Mar
Externally publishedYes

Fingerprint

Electropolymerization
Electrocatalysts
electrode
Oxygen
Soot
oxygen
Electrodes
Carbon black
catalyst
Catalyst activity
black carbon
Carbon
Nanoparticles
carbon
Noble Gases
Graphite electrodes
Catalysts
Pyrroles
Condensation reactions
Electrons

Keywords

  • Electrocatalysts
  • Electropolymerization
  • Oxygen reduction
  • Porphyrin complex

ASJC Scopus subject areas

  • Polymers and Plastics
  • Environmental Science(all)
  • Materials Science (miscellaneous)
  • Chemical Engineering (miscellaneous)
  • Ceramics and Composites

Cite this

Novel electrocatalysts for oxygen reduction using cobaltporphyrins that undergo facile electropolymerization. / Yuasa, Makoto; Oyaizu, Kenichi; Yamaguchi, Aritomo; Imai, Takuya; Kitao, Mizuki.

In: Kobunshi Ronbunshu, Vol. 63, No. 3, 03.2006, p. 182-188.

Research output: Contribution to journalArticle

Yuasa, Makoto ; Oyaizu, Kenichi ; Yamaguchi, Aritomo ; Imai, Takuya ; Kitao, Mizuki. / Novel electrocatalysts for oxygen reduction using cobaltporphyrins that undergo facile electropolymerization. In: Kobunshi Ronbunshu. 2006 ; Vol. 63, No. 3. pp. 182-188.
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AU - Kitao, Mizuki

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AB - [Meso-tetra (thiophen-3-yl)porphinato]cobalt (II) (CoT3ThP) complex, which undergoes facile electropolymerization, was synthesized by the dehydro-condensation reaction of pyrrole and 3-thienylaldehyde. The electroconductive thin film of CoT3ThP interconnected by 2,5-thienylene chains, was produced at the glassy carbon electrode by electrolysis. The catalytic activity for oxygen reduction at the modified electrode was evaluated by cyclic voltammetry. The catalytic current for the O2 reduction appeared near Ep = 0.2 V vs. SCE. It was found that the electrode modified with CoT3ThP film has a higher stability than that modified with porphyrin by absorption. Next, we chose carbon black with a high surface-area as a catalyst support, and CoT3ThP was electropolymerized under the condition of suspension of carbon black in an electrolyte solution. We found that the polymerized CoT3ThP was produced on the surface of the carbon nanoparticle. The carbon nanoparticles modified with polymerized CoT3ThP (polyCoT3ThP/C) were suspended in a Nafion solution, and a pseudo MEA (Membrane Electrode Assembly) was made by casting polyCoT3ThP/C on an edge-plane pyrolytic graphite electrode. The polyCoT3ThP/C catalyst was found to reduce O2 mainly with four electrons (the number of electrons transferred n=3.8) at a positive potential of Ep = 0.44 V vs. SCE. The catalytic activity of polyCoT3ThP/C was improved by heat treatment under an inert gas atmosphere (Ep = 0.47 V vs. SCE, n = 3.8). The results show the possibility of a novel cathode catalyst for use in fuel cells.

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