Novel regioselection in insertion of a 1,4-disubstituted-1,3-enyne into ruthenium-hydrogen bonds

Yasuo Wakatsuki, Hiroshi Yamazaki, Yooichiroh Maruyama, Isao Shimizu

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29 Citations (Scopus)

Abstract

The reaction of a conjugated enyne, cis-(Me3Si)CH= CHC≡CSiMe3, with [RuCl(CO)H(PPh3)3] gives a quantitative yield of a stable complex whose molecular structure is formally regarded as the result of either 1,2-addition of the H-Ru to the double bond or 1,4-addition of the H-Ru to the conjugated enyne; the former bonding scheme operates when the enyne is hydrogenated by [Ru(CO)H2 (PPh 3)3] or [RuH2(PPh3)4], the sole product being Me3SiCH2CH2C≡ CSiMe3.

Original languageEnglish
Pages (from-to)261-263
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number4
DOIs
Publication statusPublished - 1991

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ASJC Scopus subject areas

  • Molecular Medicine

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