Novel TTF vinylogues containing phenyl groups at the vinyl positions

M. Osada; T. Kumagai; M. Sugimoto; J. Nishida; Y. Yamashita

doi:10.1016/j.synthmet.2005.07.157

Novel TTF vinylogues containing phenyl groups at the vinyl positions

M. Osada, T. Kumagai, M. Sugimoto, J. Nishida, Y. Yamashita

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Novel TTF vinylogues containing phenyl substituents at the vinyl positions were prepared by using oxidative coupling reactions of the 1,4-dithiafulvenes, where fused-pyrazine rings, 1,3-dithiole-2-thione rings, acenaphtho[1,2-b][1,4]dithiine units and ethylenedioxy groups were introduced at the 1,3-dithiole parts. Mono-phenyl substituted derivatives were also prepared to reduce the steric interactions. The cyclic voltammetry and X-ray structure studies revealed the substituent effects on the redox behavior.

Original language	English
Pages (from-to)	429-432
Number of pages	4
Journal	Synthetic Metals
Volume	152
Issue number	1-3
DOIs	https://doi.org/10.1016/j.synthmet.2005.07.157
Publication status	Published - 2005 Sep 20
Externally published	Yes

Keywords

Coupling reactions
Diffraction and scattering
Electrochemical methods
Heterocyclic synthesis
Organic conductors based on radical cation and/or anion salts
X-ray emission

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Materials Chemistry
Polymers and Plastics

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title = "Novel TTF vinylogues containing phenyl groups at the vinyl positions",

abstract = "Novel TTF vinylogues containing phenyl substituents at the vinyl positions were prepared by using oxidative coupling reactions of the 1,4-dithiafulvenes, where fused-pyrazine rings, 1,3-dithiole-2-thione rings, acenaphtho[1,2-b][1,4]dithiine units and ethylenedioxy groups were introduced at the 1,3-dithiole parts. Mono-phenyl substituted derivatives were also prepared to reduce the steric interactions. The cyclic voltammetry and X-ray structure studies revealed the substituent effects on the redox behavior.",

keywords = "Coupling reactions, Diffraction and scattering, Electrochemical methods, Heterocyclic synthesis, Organic conductors based on radical cation and/or anion salts, X-ray emission",

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year = "2005",

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doi = "10.1016/j.synthmet.2005.07.157",

language = "English",

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journal = "Synthetic Metals",

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T1 - Novel TTF vinylogues containing phenyl groups at the vinyl positions

AU - Osada, M.

AU - Kumagai, T.

AU - Sugimoto, M.

AU - Nishida, J.

AU - Yamashita, Y.

PY - 2005/9/20

Y1 - 2005/9/20

N2 - Novel TTF vinylogues containing phenyl substituents at the vinyl positions were prepared by using oxidative coupling reactions of the 1,4-dithiafulvenes, where fused-pyrazine rings, 1,3-dithiole-2-thione rings, acenaphtho[1,2-b][1,4]dithiine units and ethylenedioxy groups were introduced at the 1,3-dithiole parts. Mono-phenyl substituted derivatives were also prepared to reduce the steric interactions. The cyclic voltammetry and X-ray structure studies revealed the substituent effects on the redox behavior.

AB - Novel TTF vinylogues containing phenyl substituents at the vinyl positions were prepared by using oxidative coupling reactions of the 1,4-dithiafulvenes, where fused-pyrazine rings, 1,3-dithiole-2-thione rings, acenaphtho[1,2-b][1,4]dithiine units and ethylenedioxy groups were introduced at the 1,3-dithiole parts. Mono-phenyl substituted derivatives were also prepared to reduce the steric interactions. The cyclic voltammetry and X-ray structure studies revealed the substituent effects on the redox behavior.

KW - Coupling reactions

KW - Diffraction and scattering

KW - Electrochemical methods

KW - Heterocyclic synthesis

KW - Organic conductors based on radical cation and/or anion salts

KW - X-ray emission

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JF - Synthetic Metals

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ER -

Novel TTF vinylogues containing phenyl groups at the vinyl positions

Abstract

Keywords

ASJC Scopus subject areas

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