Abstract
Novel TTF vinylogues containing phenyl substituents at the vinyl positions were prepared by using oxidative coupling reactions of the 1,4-dithiafulvenes, where fused-pyrazine rings, 1,3-dithiole-2-thione rings, acenaphtho[1,2-b][1,4]dithiine units and ethylenedioxy groups were introduced at the 1,3-dithiole parts. Mono-phenyl substituted derivatives were also prepared to reduce the steric interactions. The cyclic voltammetry and X-ray structure studies revealed the substituent effects on the redox behavior.
| Original language | English |
|---|---|
| Pages (from-to) | 429-432 |
| Number of pages | 4 |
| Journal | Synthetic Metals |
| Volume | 152 |
| Issue number | 1-3 |
| DOIs | |
| Publication status | Published - 2005 Sep 20 |
| Externally published | Yes |
Fingerprint
Keywords
- Coupling reactions
- Diffraction and scattering
- Electrochemical methods
- Heterocyclic synthesis
- Organic conductors based on radical cation and/or anion salts
- X-ray emission
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Materials Chemistry
- Polymers and Plastics
Cite this
Novel TTF vinylogues containing phenyl groups at the vinyl positions. / Osada, M.; Kumagai, T.; Sugimoto, M.; Nishida, J.; Yamashita, Y.
In: Synthetic Metals, Vol. 152, No. 1-3, 20.09.2005, p. 429-432.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Novel TTF vinylogues containing phenyl groups at the vinyl positions
AU - Osada, M.
AU - Kumagai, T.
AU - Sugimoto, M.
AU - Nishida, J.
AU - Yamashita, Y.
PY - 2005/9/20
Y1 - 2005/9/20
N2 - Novel TTF vinylogues containing phenyl substituents at the vinyl positions were prepared by using oxidative coupling reactions of the 1,4-dithiafulvenes, where fused-pyrazine rings, 1,3-dithiole-2-thione rings, acenaphtho[1,2-b][1,4]dithiine units and ethylenedioxy groups were introduced at the 1,3-dithiole parts. Mono-phenyl substituted derivatives were also prepared to reduce the steric interactions. The cyclic voltammetry and X-ray structure studies revealed the substituent effects on the redox behavior.
AB - Novel TTF vinylogues containing phenyl substituents at the vinyl positions were prepared by using oxidative coupling reactions of the 1,4-dithiafulvenes, where fused-pyrazine rings, 1,3-dithiole-2-thione rings, acenaphtho[1,2-b][1,4]dithiine units and ethylenedioxy groups were introduced at the 1,3-dithiole parts. Mono-phenyl substituted derivatives were also prepared to reduce the steric interactions. The cyclic voltammetry and X-ray structure studies revealed the substituent effects on the redox behavior.
KW - Coupling reactions
KW - Diffraction and scattering
KW - Electrochemical methods
KW - Heterocyclic synthesis
KW - Organic conductors based on radical cation and/or anion salts
KW - X-ray emission
UR - http://www.scopus.com/inward/record.url?scp=24644467830&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=24644467830&partnerID=8YFLogxK
U2 - 10.1016/j.synthmet.2005.07.157
DO - 10.1016/j.synthmet.2005.07.157
M3 - Article
AN - SCOPUS:24644467830
VL - 152
SP - 429
EP - 432
JO - Synthetic Metals
JF - Synthetic Metals
SN - 0379-6779
IS - 1-3
ER -