Novel TTF vinylogues containing phenyl groups at the vinyl positions

M. Osada, T. Kumagai, M. Sugimoto, J. Nishida, Y. Yamashita

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Novel TTF vinylogues containing phenyl substituents at the vinyl positions were prepared by using oxidative coupling reactions of the 1,4-dithiafulvenes, where fused-pyrazine rings, 1,3-dithiole-2-thione rings, acenaphtho[1,2-b][1,4]dithiine units and ethylenedioxy groups were introduced at the 1,3-dithiole parts. Mono-phenyl substituted derivatives were also prepared to reduce the steric interactions. The cyclic voltammetry and X-ray structure studies revealed the substituent effects on the redox behavior.

Original languageEnglish
Pages (from-to)429-432
Number of pages4
JournalSynthetic Metals
Volume152
Issue number1-3
DOIs
Publication statusPublished - 2005 Sep 20
Externally publishedYes

Fingerprint

Pyrazines
Thiones
Cyclic voltammetry
Derivatives
X rays
pyrazines
rings
x rays
interactions
Oxidation-Reduction

Keywords

  • Coupling reactions
  • Diffraction and scattering
  • Electrochemical methods
  • Heterocyclic synthesis
  • Organic conductors based on radical cation and/or anion salts
  • X-ray emission

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry
  • Polymers and Plastics

Cite this

Osada, M., Kumagai, T., Sugimoto, M., Nishida, J., & Yamashita, Y. (2005). Novel TTF vinylogues containing phenyl groups at the vinyl positions. Synthetic Metals, 152(1-3), 429-432. https://doi.org/10.1016/j.synthmet.2005.07.157

Novel TTF vinylogues containing phenyl groups at the vinyl positions. / Osada, M.; Kumagai, T.; Sugimoto, M.; Nishida, J.; Yamashita, Y.

In: Synthetic Metals, Vol. 152, No. 1-3, 20.09.2005, p. 429-432.

Research output: Contribution to journalArticle

Osada, M, Kumagai, T, Sugimoto, M, Nishida, J & Yamashita, Y 2005, 'Novel TTF vinylogues containing phenyl groups at the vinyl positions', Synthetic Metals, vol. 152, no. 1-3, pp. 429-432. https://doi.org/10.1016/j.synthmet.2005.07.157
Osada M, Kumagai T, Sugimoto M, Nishida J, Yamashita Y. Novel TTF vinylogues containing phenyl groups at the vinyl positions. Synthetic Metals. 2005 Sep 20;152(1-3):429-432. https://doi.org/10.1016/j.synthmet.2005.07.157
Osada, M. ; Kumagai, T. ; Sugimoto, M. ; Nishida, J. ; Yamashita, Y. / Novel TTF vinylogues containing phenyl groups at the vinyl positions. In: Synthetic Metals. 2005 ; Vol. 152, No. 1-3. pp. 429-432.
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