Novel TTF vinylogues containing phenyl groups at the vinyl positions

M. Osada, T. Kumagai, M. Sugimoto, J. Nishida, Y. Yamashita

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Novel TTF vinylogues containing phenyl substituents at the vinyl positions were prepared by using oxidative coupling reactions of the 1,4-dithiafulvenes, where fused-pyrazine rings, 1,3-dithiole-2-thione rings, acenaphtho[1,2-b][1,4]dithiine units and ethylenedioxy groups were introduced at the 1,3-dithiole parts. Mono-phenyl substituted derivatives were also prepared to reduce the steric interactions. The cyclic voltammetry and X-ray structure studies revealed the substituent effects on the redox behavior.

Original languageEnglish
Pages (from-to)429-432
Number of pages4
JournalSynthetic Metals
Volume152
Issue number1-3
DOIs
Publication statusPublished - 2005 Sep 20
Externally publishedYes

Keywords

  • Coupling reactions
  • Diffraction and scattering
  • Electrochemical methods
  • Heterocyclic synthesis
  • Organic conductors based on radical cation and/or anion salts
  • X-ray emission

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry
  • Polymers and Plastics

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  • Cite this

    Osada, M., Kumagai, T., Sugimoto, M., Nishida, J., & Yamashita, Y. (2005). Novel TTF vinylogues containing phenyl groups at the vinyl positions. Synthetic Metals, 152(1-3), 429-432. https://doi.org/10.1016/j.synthmet.2005.07.157