Nucleation of Ga2O3 nanocrystals in the K2O-Ga2O3-SiO2 glass system

R. Ceccato, R. Dal Maschio, S. Gialanella, G. Mariotto, M. Montagna, F. Rossi, M. Ferrari, K. E. Lipinska-Kalita, Y. Ohki

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Abstract

A multitechnique approach, consisting of x-ray diffraction, differential thermal analysis, low frequency Raman scattering from the acoustic vibrations of nanoclusters, and transmission electron microscopy associated with selected area diffraction, has been used to study the nucleation and crystallization processes in SiO2-Ga2O3-K2O glasses. The specific aim was to determine the structure and the size distribution of nanoparticles embedded in the glass matrix. It has been found that nearly spherical nanocrystals of β-Ga2O3, with a size of ∼2-3 nm, nucleate during thermal treatments at 900°C. Crystallization was observed after annealing at higher temperature. The amount of the crystalline phase and the mean size of the nanocrystals increased with heat treatment, time and temperature. β-Ga2O3 was the only crystalline phase to appear in all glass samples.

Original languageEnglish
Pages (from-to)2522-2527
Number of pages6
JournalJournal of Applied Physics
Volume90
Issue number5
DOIs
Publication statusPublished - 2001 Sep 1

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ASJC Scopus subject areas

  • Physics and Astronomy(all)

Cite this

Ceccato, R., Dal Maschio, R., Gialanella, S., Mariotto, G., Montagna, M., Rossi, F., Ferrari, M., Lipinska-Kalita, K. E., & Ohki, Y. (2001). Nucleation of Ga2O3 nanocrystals in the K2O-Ga2O3-SiO2 glass system. Journal of Applied Physics, 90(5), 2522-2527. https://doi.org/10.1063/1.1365426