Nucleobase-Induced Supramolecular Polymerization in the Solid State

Stuart J. Rowan; Phiriyatorn Suwanmala; Sona Sivakova

doi:10.1002/pola.10967

Nucleobase-Induced Supramolecular Polymerization in the Solid State

Stuart J. Rowan, Phiriyatorn Suwanmala, Sona Sivakova

Research output: Contribution to journal › Article › peer-review

62 Citations (Scopus)

Abstract

Supramolecular polymerization, that is, the self-assembly of polymer-like materials through the utilization of the noncovalent bond, has been a developing area of research over the last decade. In this article, we report the synthesis of nucleobaseterminated (N⁶-anisoyl-adenine and thymine) low-molecular-weight poly(tetrahydrofuran) macromonomers (-1). The adenine-derived supramolecular telechelic polymer self-assembled in the solid state to yield materials with film- and fiber-forming capabilities. This material was thermally reversible and exhibited a ceiling temperature, above which a drop in viscosity was observed and fibers could no longer be obtained.

Original language	English
Pages (from-to)	3589-3596
Number of pages	8
Journal	Journal of Polymer Science, Part A: Polymer Chemistry
Volume	41
Issue number	22
DOIs	https://doi.org/10.1002/pola.10967
Publication status	Published - 2003 Nov 15
Externally published	Yes

Keywords

Macromonomers
Nucleobase
Reversible polymers
Self-assembly
Supramolecular structures

ASJC Scopus subject areas

Polymers and Plastics
Materials Chemistry

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abstract = "Supramolecular polymerization, that is, the self-assembly of polymer-like materials through the utilization of the noncovalent bond, has been a developing area of research over the last decade. In this article, we report the synthesis of nucleobaseterminated (N6-anisoyl-adenine and thymine) low-molecular-weight poly(tetrahydrofuran) macromonomers (-1). The adenine-derived supramolecular telechelic polymer self-assembled in the solid state to yield materials with film- and fiber-forming capabilities. This material was thermally reversible and exhibited a ceiling temperature, above which a drop in viscosity was observed and fibers could no longer be obtained.",

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AU - Suwanmala, Phiriyatorn

AU - Sivakova, Sona

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AB - Supramolecular polymerization, that is, the self-assembly of polymer-like materials through the utilization of the noncovalent bond, has been a developing area of research over the last decade. In this article, we report the synthesis of nucleobaseterminated (N6-anisoyl-adenine and thymine) low-molecular-weight poly(tetrahydrofuran) macromonomers (-1). The adenine-derived supramolecular telechelic polymer self-assembled in the solid state to yield materials with film- and fiber-forming capabilities. This material was thermally reversible and exhibited a ceiling temperature, above which a drop in viscosity was observed and fibers could no longer be obtained.

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KW - Reversible polymers

KW - Self-assembly

KW - Supramolecular structures

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Nucleobase-Induced Supramolecular Polymerization in the Solid State

Abstract

Keywords

ASJC Scopus subject areas

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