Nucleophilic radical substitution of polychloroazines

Nobuhiro Kanomata, Mamoru Igarashi, Masaru Tada

    Research output: Contribution to journalArticle

    4 Citations (Scopus)

    Abstract

    Polychloroazines (1-6) are susceptible to homolytic chlorine substitution by alkyl radicals. In general, the chlorine at the ortho-position to the ring nitrogen is readily replaced by an alkyl radical like adamantyl and tert-butyl. However, the chlorine at the C2-position of pyrimidine did not show any sign of the radical substitution. The reactivity decreases in the order of adamantyl, tert-butyl, and isopropyl radicals.

    Original languageEnglish
    Pages (from-to)1127-1138
    Number of pages12
    JournalHeterocycles
    Volume36
    Issue number5
    Publication statusPublished - 1993 May 1

    Fingerprint

    Chlorine
    Substitution reactions
    Nitrogen

    ASJC Scopus subject areas

    • Organic Chemistry

    Cite this

    Kanomata, N., Igarashi, M., & Tada, M. (1993). Nucleophilic radical substitution of polychloroazines. Heterocycles, 36(5), 1127-1138.

    Nucleophilic radical substitution of polychloroazines. / Kanomata, Nobuhiro; Igarashi, Mamoru; Tada, Masaru.

    In: Heterocycles, Vol. 36, No. 5, 01.05.1993, p. 1127-1138.

    Research output: Contribution to journalArticle

    Kanomata, N, Igarashi, M & Tada, M 1993, 'Nucleophilic radical substitution of polychloroazines', Heterocycles, vol. 36, no. 5, pp. 1127-1138.
    Kanomata N, Igarashi M, Tada M. Nucleophilic radical substitution of polychloroazines. Heterocycles. 1993 May 1;36(5):1127-1138.
    Kanomata, Nobuhiro ; Igarashi, Mamoru ; Tada, Masaru. / Nucleophilic radical substitution of polychloroazines. In: Heterocycles. 1993 ; Vol. 36, No. 5. pp. 1127-1138.
    @article{2125f0e435124a5d85f107d4a188ed7c,
    title = "Nucleophilic radical substitution of polychloroazines",
    abstract = "Polychloroazines (1-6) are susceptible to homolytic chlorine substitution by alkyl radicals. In general, the chlorine at the ortho-position to the ring nitrogen is readily replaced by an alkyl radical like adamantyl and tert-butyl. However, the chlorine at the C2-position of pyrimidine did not show any sign of the radical substitution. The reactivity decreases in the order of adamantyl, tert-butyl, and isopropyl radicals.",
    author = "Nobuhiro Kanomata and Mamoru Igarashi and Masaru Tada",
    year = "1993",
    month = "5",
    day = "1",
    language = "English",
    volume = "36",
    pages = "1127--1138",
    journal = "Heterocycles",
    issn = "0385-5414",
    publisher = "Japan Institute of Heterocyclic Chemistry",
    number = "5",

    }

    TY - JOUR

    T1 - Nucleophilic radical substitution of polychloroazines

    AU - Kanomata, Nobuhiro

    AU - Igarashi, Mamoru

    AU - Tada, Masaru

    PY - 1993/5/1

    Y1 - 1993/5/1

    N2 - Polychloroazines (1-6) are susceptible to homolytic chlorine substitution by alkyl radicals. In general, the chlorine at the ortho-position to the ring nitrogen is readily replaced by an alkyl radical like adamantyl and tert-butyl. However, the chlorine at the C2-position of pyrimidine did not show any sign of the radical substitution. The reactivity decreases in the order of adamantyl, tert-butyl, and isopropyl radicals.

    AB - Polychloroazines (1-6) are susceptible to homolytic chlorine substitution by alkyl radicals. In general, the chlorine at the ortho-position to the ring nitrogen is readily replaced by an alkyl radical like adamantyl and tert-butyl. However, the chlorine at the C2-position of pyrimidine did not show any sign of the radical substitution. The reactivity decreases in the order of adamantyl, tert-butyl, and isopropyl radicals.

    UR - http://www.scopus.com/inward/record.url?scp=8544241372&partnerID=8YFLogxK

    UR - http://www.scopus.com/inward/citedby.url?scp=8544241372&partnerID=8YFLogxK

    M3 - Article

    VL - 36

    SP - 1127

    EP - 1138

    JO - Heterocycles

    JF - Heterocycles

    SN - 0385-5414

    IS - 5

    ER -