Nucleophilic radical substitution of polychloroazines

Nobuhiro Kanomata, Mamoru Igarashi, Masaru Tada

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Polychloroazines (1-6) are susceptible to homolytic chlorine substitution by alkyl radicals. In general, the chlorine at the ortho-position to the ring nitrogen is readily replaced by an alkyl radical like adamantyl and tert-butyl. However, the chlorine at the C2-position of pyrimidine did not show any sign of the radical substitution. The reactivity decreases in the order of adamantyl, tert-butyl, and isopropyl radicals.

Original languageEnglish
Pages (from-to)1127-1138
Number of pages12
JournalHeterocycles
Volume36
Issue number5
Publication statusPublished - 1993 May 1

ASJC Scopus subject areas

  • Analytical Chemistry
  • Pharmacology
  • Organic Chemistry

Fingerprint Dive into the research topics of 'Nucleophilic radical substitution of polychloroazines'. Together they form a unique fingerprint.

  • Cite this

    Kanomata, N., Igarashi, M., & Tada, M. (1993). Nucleophilic radical substitution of polychloroazines. Heterocycles, 36(5), 1127-1138.