Observation and dynamics of "charge-transfer isomers"

Tasuku Ito, Naoyuki Imai, Tadashi Yamaguchi, Tomohiko Hamaguchi, Casey H. Londergan, Clifford P. Kubiak

Research output: Contribution to journalArticle

54 Citations (Scopus)

Abstract

Upon electrochemical reduction, asymmetrically substituted dimers of Ru3 clusters [Ru3O(OAc)6(L)(CO)(μ-pz)Ru 3O-(OAc)6(L′)(CO)] (pz = pyrazine, L and L′ are N ligands), exhibit IR spectral line coalescence in the νCO region. The IR spectra suggest the existence of two possible "charge-transfer isomers" for example, [A--B] and [A-B -], in which A and B represent different Ru3 moieties.

Original languageEnglish
Pages (from-to)1376-1381
Number of pages6
JournalAngewandte Chemie - International Edition
Volume43
Issue number11
DOIs
Publication statusPublished - 2004 Mar 5

Keywords

  • Charge transfer
  • Electrochemistry
  • Electron transfer
  • IR spectroscopy
  • Mixed-valent compounds

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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    Ito, T., Imai, N., Yamaguchi, T., Hamaguchi, T., Londergan, C. H., & Kubiak, C. P. (2004). Observation and dynamics of "charge-transfer isomers". Angewandte Chemie - International Edition, 43(11), 1376-1381. https://doi.org/10.1002/anie.200353221