Abstract
Upon electrochemical reduction, asymmetrically substituted dimers of Ru3 clusters [Ru3O(OAc)6(L)(CO)(μ-pz)Ru 3O-(OAc)6(L′)(CO)] (pz = pyrazine, L and L′ are N ligands), exhibit IR spectral line coalescence in the νCO region. The IR spectra suggest the existence of two possible "charge-transfer isomers" for example, [A--B] and [A-B -], in which A and B represent different Ru3 moieties.
Original language | English |
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Pages (from-to) | 1376-1381 |
Number of pages | 6 |
Journal | Angewandte Chemie - International Edition |
Volume | 43 |
Issue number | 11 |
DOIs | |
Publication status | Published - 2004 Mar 5 |
Externally published | Yes |
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Keywords
- Charge transfer
- Electrochemistry
- Electron transfer
- IR spectroscopy
- Mixed-valent compounds
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Observation and dynamics of "charge-transfer isomers". / Ito, Tasuku; Imai, Naoyuki; Yamaguchi, Tadashi; Hamaguchi, Tomohiko; Londergan, Casey H.; Kubiak, Clifford P.
In: Angewandte Chemie - International Edition, Vol. 43, No. 11, 05.03.2004, p. 1376-1381.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Observation and dynamics of "charge-transfer isomers"
AU - Ito, Tasuku
AU - Imai, Naoyuki
AU - Yamaguchi, Tadashi
AU - Hamaguchi, Tomohiko
AU - Londergan, Casey H.
AU - Kubiak, Clifford P.
PY - 2004/3/5
Y1 - 2004/3/5
N2 - Upon electrochemical reduction, asymmetrically substituted dimers of Ru3 clusters [Ru3O(OAc)6(L)(CO)(μ-pz)Ru 3O-(OAc)6(L′)(CO)] (pz = pyrazine, L and L′ are N ligands), exhibit IR spectral line coalescence in the νCO region. The IR spectra suggest the existence of two possible "charge-transfer isomers" for example, [A--B] and [A-B -], in which A and B represent different Ru3 moieties.
AB - Upon electrochemical reduction, asymmetrically substituted dimers of Ru3 clusters [Ru3O(OAc)6(L)(CO)(μ-pz)Ru 3O-(OAc)6(L′)(CO)] (pz = pyrazine, L and L′ are N ligands), exhibit IR spectral line coalescence in the νCO region. The IR spectra suggest the existence of two possible "charge-transfer isomers" for example, [A--B] and [A-B -], in which A and B represent different Ru3 moieties.
KW - Charge transfer
KW - Electrochemistry
KW - Electron transfer
KW - IR spectroscopy
KW - Mixed-valent compounds
UR - http://www.scopus.com/inward/record.url?scp=4544229374&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=4544229374&partnerID=8YFLogxK
U2 - 10.1002/anie.200353221
DO - 10.1002/anie.200353221
M3 - Article
C2 - 15368411
AN - SCOPUS:4544229374
VL - 43
SP - 1376
EP - 1381
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 11
ER -