On the correlations between Sr: Ca substitution and structural modulation in the Bi-2212 phase

Y. Oikawa, P. P. Saligan, K. Koizumi, H. Enomoto, Y. Takano, K. Sekizawa, Etsuo Uchida, H. Ozaki

    Research output: Contribution to journalArticle

    Abstract

    XPS and chemical titration both were carried out on Bi2+xSrl.8CaCu2Oz and Bi2Srl.8-yCal+yCu20zprepared by solid state reaction in order to investigate the correlation between the structural modulation and the mutual substitution of atoms. There was no clear evidence about the correlation between the modulation period by XRD and the site occupancies of Sr and Ca by XPS. However, there was a tendency that Bi mean valence by titration inereased with increasing excess oxygen content and modulation period. The former one indicates the charge compensation and the latter one suggests the possibility of the origin of the structural modulation except for the excess oxygen.

    Original languageEnglish
    Pages (from-to)1423-1424
    Number of pages2
    JournalCzechoslovak Journal of Physics
    Volume46
    Issue numberSUPPL. 3
    DOIs
    Publication statusPublished - 1996

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    substitutes
    modulation
    titration
    oxygen
    tendencies
    solid state
    valence
    atoms

    ASJC Scopus subject areas

    • Physics and Astronomy(all)

    Cite this

    Oikawa, Y., Saligan, P. P., Koizumi, K., Enomoto, H., Takano, Y., Sekizawa, K., ... Ozaki, H. (1996). On the correlations between Sr: Ca substitution and structural modulation in the Bi-2212 phase. Czechoslovak Journal of Physics, 46(SUPPL. 3), 1423-1424. https://doi.org/10.1007/BF02562826

    On the correlations between Sr : Ca substitution and structural modulation in the Bi-2212 phase. / Oikawa, Y.; Saligan, P. P.; Koizumi, K.; Enomoto, H.; Takano, Y.; Sekizawa, K.; Uchida, Etsuo; Ozaki, H.

    In: Czechoslovak Journal of Physics, Vol. 46, No. SUPPL. 3, 1996, p. 1423-1424.

    Research output: Contribution to journalArticle

    Oikawa, Y, Saligan, PP, Koizumi, K, Enomoto, H, Takano, Y, Sekizawa, K, Uchida, E & Ozaki, H 1996, 'On the correlations between Sr: Ca substitution and structural modulation in the Bi-2212 phase', Czechoslovak Journal of Physics, vol. 46, no. SUPPL. 3, pp. 1423-1424. https://doi.org/10.1007/BF02562826
    Oikawa, Y. ; Saligan, P. P. ; Koizumi, K. ; Enomoto, H. ; Takano, Y. ; Sekizawa, K. ; Uchida, Etsuo ; Ozaki, H. / On the correlations between Sr : Ca substitution and structural modulation in the Bi-2212 phase. In: Czechoslovak Journal of Physics. 1996 ; Vol. 46, No. SUPPL. 3. pp. 1423-1424.
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    abstract = "XPS and chemical titration both were carried out on Bi2+xSrl.8CaCu2Oz and Bi2Srl.8-yCal+yCu20zprepared by solid state reaction in order to investigate the correlation between the structural modulation and the mutual substitution of atoms. There was no clear evidence about the correlation between the modulation period by XRD and the site occupancies of Sr and Ca by XPS. However, there was a tendency that Bi mean valence by titration inereased with increasing excess oxygen content and modulation period. The former one indicates the charge compensation and the latter one suggests the possibility of the origin of the structural modulation except for the excess oxygen.",
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    T2 - Ca substitution and structural modulation in the Bi-2212 phase

    AU - Oikawa, Y.

    AU - Saligan, P. P.

    AU - Koizumi, K.

    AU - Enomoto, H.

    AU - Takano, Y.

    AU - Sekizawa, K.

    AU - Uchida, Etsuo

    AU - Ozaki, H.

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    AB - XPS and chemical titration both were carried out on Bi2+xSrl.8CaCu2Oz and Bi2Srl.8-yCal+yCu20zprepared by solid state reaction in order to investigate the correlation between the structural modulation and the mutual substitution of atoms. There was no clear evidence about the correlation between the modulation period by XRD and the site occupancies of Sr and Ca by XPS. However, there was a tendency that Bi mean valence by titration inereased with increasing excess oxygen content and modulation period. The former one indicates the charge compensation and the latter one suggests the possibility of the origin of the structural modulation except for the excess oxygen.

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