On the reaction of (vinylimino)phosphoranes and related compounds synthesis and properties of novel 1,6-methanocyclodeca[b]cyclohepta[d]pyrrole

Makoto Nitta, Hiroyuki Kawaji, Nobuhiro Kanomata

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

The title compound was synthesized by thermal reaction of 3-phosphoranylidene-amino-1,6-methano[10]annulene with 2-chlorotropone in a single step. The examination of 1H NMR spectrum revealed that there is little contribution of peripheral 18-π electron conjugation, but it is rather composed of 1-azaazulene and methano[10]annulene moieties.

Original languageEnglish
Pages (from-to)251-254
Number of pages4
JournalTetrahedron Letters
Volume33
Issue number2
DOIs
Publication statusPublished - 1992

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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