On the shape of the cyclic voltammetry peaks of species irreversibly adsorbed on electrode surfaces

Research output: Contribution to journalArticle

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Abstract

A theory has been developed which accounts for certain deviations from the ideal cyclic voltammetric behavior of molecules adsorbed irreversibly on electrode surfaces. This new model considers explicitly the interactions of the electric field at the interface with the permanent dipole moment of the adsorbed species. Good quantitative agreement has been obtained with experimental data reported earlier in the literature.

Original languageEnglish
Pages (from-to)33-38
Number of pages6
JournalJournal of Electroanalytical Chemistry
Volume188
Issue number1-2
DOIs
Publication statusPublished - 1985 Jun 25
Externally publishedYes

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Dipole moment
Cyclic voltammetry
Electric fields
Electrodes
Molecules

ASJC Scopus subject areas

  • Analytical Chemistry
  • Chemical Engineering(all)
  • Electrochemistry

Cite this

On the shape of the cyclic voltammetry peaks of species irreversibly adsorbed on electrode surfaces. / Gerischer, H.; Scherson, Daniel Alberto.

In: Journal of Electroanalytical Chemistry, Vol. 188, No. 1-2, 25.06.1985, p. 33-38.

Research output: Contribution to journalArticle

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