Abstract
A detailed study of the voltammetry curves of Pt (111) prepared by the flame method has provided strong evidence that the anomalous features reported originally by Clavilier et al., are associated with the specific adsorption of anions rather than hydrogen adsorption. In the case of HClO4 or HF electrolytes such features are attributed to the adsorption of hydroxy ions (incipient oxidation) whereas in H2SO4 they are caused by the adsorption of sulfate or bisulfate ions.
| Original language | English |
|---|---|
| Pages (from-to) | 353-362 |
| Number of pages | 10 |
| Journal | Journal of Electroanalytical Chemistry |
| Volume | 200 |
| Issue number | 1-2 |
| DOIs | |
| Publication status | Published - 1986 Mar 25 |
| Externally published | Yes |
ASJC Scopus subject areas
- Analytical Chemistry
- Chemical Engineering(all)
- Electrochemistry
Fingerprint Dive into the research topics of 'On the voltammetry of curves of Pt (111) in aqueous solutions'. Together they form a unique fingerprint.
Cite this
Jaaf-Golze, K. A., Kolb, D. M., & Scherson, D. A. (1986). On the voltammetry of curves of Pt (111) in aqueous solutions. Journal of Electroanalytical Chemistry, 200(1-2), 353-362. https://doi.org/10.1016/0022-0728(86)90067-7