Abstract
A detailed study of the voltammetry curves of Pt (111) prepared by the flame method has provided strong evidence that the anomalous features reported originally by Clavilier et al., are associated with the specific adsorption of anions rather than hydrogen adsorption. In the case of HClO4 or HF electrolytes such features are attributed to the adsorption of hydroxy ions (incipient oxidation) whereas in H2SO4 they are caused by the adsorption of sulfate or bisulfate ions.
| Original language | English |
|---|---|
| Pages (from-to) | 353-362 |
| Number of pages | 10 |
| Journal | Journal of Electroanalytical Chemistry |
| Volume | 200 |
| Issue number | 1-2 |
| DOIs | |
| Publication status | Published - 1986 Mar 25 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Analytical Chemistry
- Chemical Engineering(all)
- Electrochemistry
Cite this
On the voltammetry of curves of Pt (111) in aqueous solutions. / Jaaf-Golze, K. Al; Kolb, D. M.; Scherson, Daniel Alberto.
In: Journal of Electroanalytical Chemistry, Vol. 200, No. 1-2, 25.03.1986, p. 353-362.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - On the voltammetry of curves of Pt (111) in aqueous solutions
AU - Jaaf-Golze, K. Al
AU - Kolb, D. M.
AU - Scherson, Daniel Alberto
PY - 1986/3/25
Y1 - 1986/3/25
N2 - A detailed study of the voltammetry curves of Pt (111) prepared by the flame method has provided strong evidence that the anomalous features reported originally by Clavilier et al., are associated with the specific adsorption of anions rather than hydrogen adsorption. In the case of HClO4 or HF electrolytes such features are attributed to the adsorption of hydroxy ions (incipient oxidation) whereas in H2SO4 they are caused by the adsorption of sulfate or bisulfate ions.
AB - A detailed study of the voltammetry curves of Pt (111) prepared by the flame method has provided strong evidence that the anomalous features reported originally by Clavilier et al., are associated with the specific adsorption of anions rather than hydrogen adsorption. In the case of HClO4 or HF electrolytes such features are attributed to the adsorption of hydroxy ions (incipient oxidation) whereas in H2SO4 they are caused by the adsorption of sulfate or bisulfate ions.
UR - http://www.scopus.com/inward/record.url?scp=0000719279&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0000719279&partnerID=8YFLogxK
U2 - 10.1016/0022-0728(86)90067-7
DO - 10.1016/0022-0728(86)90067-7
M3 - Article
AN - SCOPUS:0000719279
VL - 200
SP - 353
EP - 362
JO - Journal of Electroanalytical Chemistry
JF - Journal of Electroanalytical Chemistry
SN - 0022-0728
IS - 1-2
ER -