One-dimensional bromo-bridged NiIII complexes [Ni(S,S-bn) 2Br]Br2 (S,S-bn =2S,3S-diaminobutane): Synthesis, physical properties, and electrostatic carrier doping

Shinya Takaishi; Masahiro Yamashita; Hiroyuki Matsuzaki; Hiroshi Okamoto; Hisaaki Tanaka; Shin Ichi Kuroda; Atsushi Goto; Tadashi Shimizu; Taishi Takenobu; Yoshihiro Iwasa

doi:10.1002/chem.200701299

One-dimensional bromo-bridged Ni^III complexes [Ni(S,S-bn) ₂Br]Br₂ (S,S-bn =2S,3S-diaminobutane): Synthesis, physical properties, and electrostatic carrier doping

Shinya Takaishi^*, Masahiro Yamashita, Hiroyuki Matsuzaki, Hiroshi Okamoto, Hisaaki Tanaka, Shin Ichi Kuroda, Atsushi Goto, Tadashi Shimizu, Taishi Takenobu, Yoshihiro Iwasa

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

A new bromo-bridged Ni^III compound has been synthesized. This compound displayed a strong antiferromagnetic interaction between spins located on Ni^III species (J = (2350 ± 500) K) that result from the strong covalency of the Ni - Br bond and the spin-Peierls transition below 150K. This was shown by the results of magnetic susceptibility and ⁸¹Br nuclear quadrupole resonance spectroscopy analysis. We succeeded in the electrostatic carrier doping of a single crystalline sample by using a field-effect transistor device. This compound also showed n-type semiconductor behavior, which can be reasonably rationalized by the existence of a small amount of Ni^II impurities.

Original language	English
Pages (from-to)	472-477
Number of pages	6
Journal	Chemistry - A European Journal
Volume	14
Issue number	2
DOIs	https://doi.org/10.1002/chem.200701299
Publication status	Published - 2008
Externally published	Yes

Keywords

Bridging ligands
Carrier doping
EPR spectroscopy
Field-effect transistors
Nickel

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1002/chem.200701299

Cite this

Takaishi, S., Yamashita, M., Matsuzaki, H., Okamoto, H., Tanaka, H., Kuroda, S. I., Goto, A., Shimizu, T., Takenobu, T., & Iwasa, Y. (2008). One-dimensional bromo-bridged Ni^III complexes [Ni(S,S-bn) ₂Br]Br₂ (S,S-bn =2S,3S-diaminobutane): Synthesis, physical properties, and electrostatic carrier doping. Chemistry - A European Journal, 14(2), 472-477. https://doi.org/10.1002/chem.200701299

Takaishi, S, Yamashita, M, Matsuzaki, H, Okamoto, H, Tanaka, H, Kuroda, SI, Goto, A, Shimizu, T, Takenobu, T & Iwasa, Y 2008, 'One-dimensional bromo-bridged Ni^III complexes [Ni(S,S-bn) ₂Br]Br₂ (S,S-bn =2S,3S-diaminobutane): Synthesis, physical properties, and electrostatic carrier doping', Chemistry - A European Journal, vol. 14, no. 2, pp. 472-477. https://doi.org/10.1002/chem.200701299

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title = "One-dimensional bromo-bridged NiIII complexes [Ni(S,S-bn) 2Br]Br2 (S,S-bn =2S,3S-diaminobutane): Synthesis, physical properties, and electrostatic carrier doping",

abstract = "A new bromo-bridged NiIII compound has been synthesized. This compound displayed a strong antiferromagnetic interaction between spins located on NiIII species (J = (2350 ± 500) K) that result from the strong covalency of the Ni - Br bond and the spin-Peierls transition below 150K. This was shown by the results of magnetic susceptibility and 81Br nuclear quadrupole resonance spectroscopy analysis. We succeeded in the electrostatic carrier doping of a single crystalline sample by using a field-effect transistor device. This compound also showed n-type semiconductor behavior, which can be reasonably rationalized by the existence of a small amount of NiII impurities.",

keywords = "Bridging ligands, Carrier doping, EPR spectroscopy, Field-effect transistors, Nickel",

author = "Shinya Takaishi and Masahiro Yamashita and Hiroyuki Matsuzaki and Hiroshi Okamoto and Hisaaki Tanaka and Kuroda, {Shin Ichi} and Atsushi Goto and Tadashi Shimizu and Taishi Takenobu and Yoshihiro Iwasa",

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AU - Takaishi, Shinya

AU - Yamashita, Masahiro

AU - Matsuzaki, Hiroyuki

AU - Okamoto, Hiroshi

AU - Tanaka, Hisaaki

AU - Kuroda, Shin Ichi

AU - Goto, Atsushi

AU - Shimizu, Tadashi

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AB - A new bromo-bridged NiIII compound has been synthesized. This compound displayed a strong antiferromagnetic interaction between spins located on NiIII species (J = (2350 ± 500) K) that result from the strong covalency of the Ni - Br bond and the spin-Peierls transition below 150K. This was shown by the results of magnetic susceptibility and 81Br nuclear quadrupole resonance spectroscopy analysis. We succeeded in the electrostatic carrier doping of a single crystalline sample by using a field-effect transistor device. This compound also showed n-type semiconductor behavior, which can be reasonably rationalized by the existence of a small amount of NiII impurities.

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KW - EPR spectroscopy

KW - Field-effect transistors

KW - Nickel

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