One-pot cross-coupling of diborylmethane for the synthesis of dithienylmethane derivatives

Kohei Endo, Takafumi Ishioka, Takanori Shibata

    Research output: Contribution to journalArticle

    11 Citations (Scopus)

    Abstract

    The one-pot palladium-catalyzed Suzuki-Miyaura cross-coupling reaction of a diborylmethane with bromothiophene derivatives realized the synthesis of various dithienylmethane derivatives. Cyclopentadithiophenes, which are promising compounds in material science, can be obtained in good yields. The in situ generation of an unstable thienylmethylboronate is a key step for the present reaction.

    Original languageEnglish
    Article numberst-2014-u0515-l
    Pages (from-to)2184-2188
    Number of pages5
    JournalSynlett
    Volume25
    Issue number15
    DOIs
    Publication statusPublished - 2014

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    Derivatives
    Palladium
    Materials science

    Keywords

    • boron
    • cross-coupling
    • heterocycles
    • organometallic reagents
    • palladium

    ASJC Scopus subject areas

    • Organic Chemistry

    Cite this

    One-pot cross-coupling of diborylmethane for the synthesis of dithienylmethane derivatives. / Endo, Kohei; Ishioka, Takafumi; Shibata, Takanori.

    In: Synlett, Vol. 25, No. 15, st-2014-u0515-l, 2014, p. 2184-2188.

    Research output: Contribution to journalArticle

    Endo, Kohei ; Ishioka, Takafumi ; Shibata, Takanori. / One-pot cross-coupling of diborylmethane for the synthesis of dithienylmethane derivatives. In: Synlett. 2014 ; Vol. 25, No. 15. pp. 2184-2188.
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