One pot synthesis of layered tetratitanate-organic intercalation compounds with the aid of macrocyclic compounds

Makoto Ogawa, Yoshinao Takizawa

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

We now report the preparation of alkylammonium-tetratitanate intercalation compounds with the aid of a macrocyclic compound, [2.2.2]-cryptand. The macrocyclic compound strongly interacts with the interlayer cation to promote the ion exchange reactions, which do not proceed in its absence. The formation of the intercalation compounds was confirmed by X-ray diffraction and elemental analysis. Since the present method is simple in operation, it is applicable to the preparation of a wide variety of inorganic-organic supramolecular systems.

Original languageEnglish
Pages (from-to)357-362
Number of pages6
JournalMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume341
Publication statusPublished - 2000

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Macrocyclic Compounds
Intercalation compounds
intercalation
preparation
synthesis
X ray diffraction analysis
Cations
interlayers
Ion exchange
Positive ions
cations
Chemical analysis
diffraction
ions
x rays

ASJC Scopus subject areas

  • Condensed Matter Physics

Cite this

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abstract = "We now report the preparation of alkylammonium-tetratitanate intercalation compounds with the aid of a macrocyclic compound, [2.2.2]-cryptand. The macrocyclic compound strongly interacts with the interlayer cation to promote the ion exchange reactions, which do not proceed in its absence. The formation of the intercalation compounds was confirmed by X-ray diffraction and elemental analysis. Since the present method is simple in operation, it is applicable to the preparation of a wide variety of inorganic-organic supramolecular systems.",
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AB - We now report the preparation of alkylammonium-tetratitanate intercalation compounds with the aid of a macrocyclic compound, [2.2.2]-cryptand. The macrocyclic compound strongly interacts with the interlayer cation to promote the ion exchange reactions, which do not proceed in its absence. The formation of the intercalation compounds was confirmed by X-ray diffraction and elemental analysis. Since the present method is simple in operation, it is applicable to the preparation of a wide variety of inorganic-organic supramolecular systems.

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