One-step synthesis of α,β-unsaturated ketones by the reaction of enol acetates with allyl methyl carbonate catalyzed by palladium and tin compounds

Jiro Tsuji, Ichiro Minami, Isao Shimizu

    Research output: Contribution to journalArticle

    34 Citations (Scopus)

    Abstract

    Enol acetates derived from saturated ketones are converted to α,β-unsaturated ketones by heating with allyl methyl carbonate in MeCN by bimetallic catalysis of palladium-phosphine complex and tin methoxide.

    Original languageEnglish
    Pages (from-to)5639-5640
    Number of pages2
    JournalTetrahedron Letters
    Volume24
    Issue number50
    DOIs
    Publication statusPublished - 1983

    Fingerprint

    Palladium compounds
    Tin Compounds
    phosphine
    Palladium
    Ketones
    Acetates
    Tin
    Catalysis
    Heating
    methyl carbonate
    allyl acetate

    ASJC Scopus subject areas

    • Biochemistry
    • Organic Chemistry
    • Drug Discovery

    Cite this

    One-step synthesis of α,β-unsaturated ketones by the reaction of enol acetates with allyl methyl carbonate catalyzed by palladium and tin compounds. / Tsuji, Jiro; Minami, Ichiro; Shimizu, Isao.

    In: Tetrahedron Letters, Vol. 24, No. 50, 1983, p. 5639-5640.

    Research output: Contribution to journalArticle

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    abstract = "Enol acetates derived from saturated ketones are converted to α,β-unsaturated ketones by heating with allyl methyl carbonate in MeCN by bimetallic catalysis of palladium-phosphine complex and tin methoxide.",
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    AU - Minami, Ichiro

    AU - Shimizu, Isao

    PY - 1983

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