Optical nonlinearity of an open-shell and degenerate π-conjugated polymer

Poly(4-oxyphenyl-1,2-phenylenevinylene) radical

Masahiro Takahashi, Shinji Yamada, Hiro Matsuda, Hachiro Nakanishi, Eishun Tsuchida, Hiroyuki Nishide

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

Third-order nonlinear optical susceptibility is enhanced by three orders of magnitude for the degenerate and high-spin ground state conjugated polymer, poly(4-oxyphenyl-1,2-phenylenevinylene), as compared with a precursor conjugated polymer with a closed-shell configuration, in a z-scan measurement.

Original languageEnglish
Pages (from-to)1853-1854
Number of pages2
JournalChemical Communications
Issue number19
Publication statusPublished - 1997

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Conjugated polymers
Ground state

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Optical nonlinearity of an open-shell and degenerate π-conjugated polymer : Poly(4-oxyphenyl-1,2-phenylenevinylene) radical. / Takahashi, Masahiro; Yamada, Shinji; Matsuda, Hiro; Nakanishi, Hachiro; Tsuchida, Eishun; Nishide, Hiroyuki.

In: Chemical Communications, No. 19, 1997, p. 1853-1854.

Research output: Contribution to journalArticle

Takahashi, Masahiro ; Yamada, Shinji ; Matsuda, Hiro ; Nakanishi, Hachiro ; Tsuchida, Eishun ; Nishide, Hiroyuki. / Optical nonlinearity of an open-shell and degenerate π-conjugated polymer : Poly(4-oxyphenyl-1,2-phenylenevinylene) radical. In: Chemical Communications. 1997 ; No. 19. pp. 1853-1854.
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