Optimized negative thermal expansion induced by gradual intermetallic charge transfer in Bi1-xSbxNiO3

Takumi Nishikubo, Yuki Sakai, Kengo Oka, Masaichiro Mizumaki, Tetsu Watanuki, Akihiko Machida, Naoyuki Maejima, Shigenori Ueda, Takashi Mizokawa, Masaki Azuma

    Research output: Contribution to journalArticle

    4 Citations (Scopus)

    Abstract

    Negative thermal expansion (NTE) induced by intermetallic charge transfer between Bi5+ and Ni2+ was observed in Bi1-xSbxNiO3 (x = 0.05 and 0.10). Bi3+ and Bi5+ had a long-range ordering in the low-temperature phase of Bi0.95Sb0.05NiO3 while the ordering was short-range in Bi0.9Sb0.01NiO3. The latter compound exhibited a continuous NTE with a linear coefficient of thermal expansion (CTE) of αL = %106 ppmK%1 without temperature hysteresis in a wide temperature range of 200-320 K.

    Original languageEnglish
    Article number061102
    JournalApplied Physics Express
    Volume11
    Issue number6
    DOIs
    Publication statusPublished - 2018 Jun 1

    Fingerprint

    Intermetallics
    intermetallics
    Charge transfer
    thermal expansion
    charge transfer
    Temperature
    Thermal expansion
    Hysteresis
    hysteresis
    temperature
    coefficients
    Negative thermal expansion

    ASJC Scopus subject areas

    • Engineering(all)
    • Physics and Astronomy(all)

    Cite this

    Nishikubo, T., Sakai, Y., Oka, K., Mizumaki, M., Watanuki, T., Machida, A., ... Azuma, M. (2018). Optimized negative thermal expansion induced by gradual intermetallic charge transfer in Bi1-xSbxNiO3 Applied Physics Express, 11(6), [061102]. https://doi.org/10.7567/APEX.11.061102

    Optimized negative thermal expansion induced by gradual intermetallic charge transfer in Bi1-xSbxNiO3 . / Nishikubo, Takumi; Sakai, Yuki; Oka, Kengo; Mizumaki, Masaichiro; Watanuki, Tetsu; Machida, Akihiko; Maejima, Naoyuki; Ueda, Shigenori; Mizokawa, Takashi; Azuma, Masaki.

    In: Applied Physics Express, Vol. 11, No. 6, 061102, 01.06.2018.

    Research output: Contribution to journalArticle

    Nishikubo, T, Sakai, Y, Oka, K, Mizumaki, M, Watanuki, T, Machida, A, Maejima, N, Ueda, S, Mizokawa, T & Azuma, M 2018, 'Optimized negative thermal expansion induced by gradual intermetallic charge transfer in Bi1-xSbxNiO3 ', Applied Physics Express, vol. 11, no. 6, 061102. https://doi.org/10.7567/APEX.11.061102
    Nishikubo, Takumi ; Sakai, Yuki ; Oka, Kengo ; Mizumaki, Masaichiro ; Watanuki, Tetsu ; Machida, Akihiko ; Maejima, Naoyuki ; Ueda, Shigenori ; Mizokawa, Takashi ; Azuma, Masaki. / Optimized negative thermal expansion induced by gradual intermetallic charge transfer in Bi1-xSbxNiO3 In: Applied Physics Express. 2018 ; Vol. 11, No. 6.
    @article{0093ea41cebf42a9b72a9421aed951bd,
    title = "Optimized negative thermal expansion induced by gradual intermetallic charge transfer in Bi1-xSbxNiO3",
    abstract = "Negative thermal expansion (NTE) induced by intermetallic charge transfer between Bi5+ and Ni2+ was observed in Bi1-xSbxNiO3 (x = 0.05 and 0.10). Bi3+ and Bi5+ had a long-range ordering in the low-temperature phase of Bi0.95Sb0.05NiO3 while the ordering was short-range in Bi0.9Sb0.01NiO3. The latter compound exhibited a continuous NTE with a linear coefficient of thermal expansion (CTE) of αL = {\%}106 ppmK{\%}1 without temperature hysteresis in a wide temperature range of 200-320 K.",
    author = "Takumi Nishikubo and Yuki Sakai and Kengo Oka and Masaichiro Mizumaki and Tetsu Watanuki and Akihiko Machida and Naoyuki Maejima and Shigenori Ueda and Takashi Mizokawa and Masaki Azuma",
    year = "2018",
    month = "6",
    day = "1",
    doi = "10.7567/APEX.11.061102",
    language = "English",
    volume = "11",
    journal = "Applied Physics Express",
    issn = "1882-0778",
    publisher = "Japan Society of Applied Physics",
    number = "6",

    }

    TY - JOUR

    T1 - Optimized negative thermal expansion induced by gradual intermetallic charge transfer in Bi1-xSbxNiO3

    AU - Nishikubo, Takumi

    AU - Sakai, Yuki

    AU - Oka, Kengo

    AU - Mizumaki, Masaichiro

    AU - Watanuki, Tetsu

    AU - Machida, Akihiko

    AU - Maejima, Naoyuki

    AU - Ueda, Shigenori

    AU - Mizokawa, Takashi

    AU - Azuma, Masaki

    PY - 2018/6/1

    Y1 - 2018/6/1

    N2 - Negative thermal expansion (NTE) induced by intermetallic charge transfer between Bi5+ and Ni2+ was observed in Bi1-xSbxNiO3 (x = 0.05 and 0.10). Bi3+ and Bi5+ had a long-range ordering in the low-temperature phase of Bi0.95Sb0.05NiO3 while the ordering was short-range in Bi0.9Sb0.01NiO3. The latter compound exhibited a continuous NTE with a linear coefficient of thermal expansion (CTE) of αL = %106 ppmK%1 without temperature hysteresis in a wide temperature range of 200-320 K.

    AB - Negative thermal expansion (NTE) induced by intermetallic charge transfer between Bi5+ and Ni2+ was observed in Bi1-xSbxNiO3 (x = 0.05 and 0.10). Bi3+ and Bi5+ had a long-range ordering in the low-temperature phase of Bi0.95Sb0.05NiO3 while the ordering was short-range in Bi0.9Sb0.01NiO3. The latter compound exhibited a continuous NTE with a linear coefficient of thermal expansion (CTE) of αL = %106 ppmK%1 without temperature hysteresis in a wide temperature range of 200-320 K.

    UR - http://www.scopus.com/inward/record.url?scp=85047949313&partnerID=8YFLogxK

    UR - http://www.scopus.com/inward/citedby.url?scp=85047949313&partnerID=8YFLogxK

    U2 - 10.7567/APEX.11.061102

    DO - 10.7567/APEX.11.061102

    M3 - Article

    AN - SCOPUS:85047949313

    VL - 11

    JO - Applied Physics Express

    JF - Applied Physics Express

    SN - 1882-0778

    IS - 6

    M1 - 061102

    ER -