Orbital states of v trimers in BaV 10O 15 detected by resonant x-ray scattering

K. Takubo, T. Kanzaki, Y. Yamasaki, H. Nakao, Y. Murakami, T. Oguchi, T. Katsufuji

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16 Citations (Scopus)

Abstract

BaV 10O 15 shows a structural phase transition associated with the trimerization of V ions at T s=123 K. We investigated the orbital states of V trimers using the technique of resonant x-ray scattering (RXS) near the V K-edge absorption energy. The ratio of the intensity between the pre-edge structure (1s to 3d transition) and the main-edge structure (1s to 4p transition) strongly depends on the reciprocal Q position of the scattering. We found that the Q position dependence is consistent with the model of orbital ordering proposed by Pen,.

Original languageEnglish
Article number085141
JournalPhysical Review B - Condensed Matter and Materials Physics
Volume86
Issue number8
DOIs
Publication statusPublished - 2012 Aug 27

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

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