Organic radical battery: Nitroxide polymers as a cathode-active material

Hiroyuki Nishide; Shigeyuki Iwasa; Yong Jin Pu; Takeo Suga; Kentaro Nakahara; Masaharu Satoh

doi:10.1016/j.electacta.2004.02.052

Organic radical battery: Nitroxide polymers as a cathode-active material

Hiroyuki Nishide^*, Shigeyuki Iwasa, Yong Jin Pu, Takeo Suga, Kentaro Nakahara, Masaharu Satoh

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

381 Citations (Scopus)

Abstract

Purely organic-derived nitroxide radicals, including their polymer derivative, poly(2,2,6,6-tetramethylpiperidinyloxy methacrylate) (PTMA), were characterized as a new class of cathode-active materials for lithium batteries. PTMA was stable at ambient conditions, had a tunable solubility and processability, and could undergo thermal runaway without any odor and ash. The nitroxide radicals displayed a reversible and very rapid redox to form their oxoammonium salts, which enabled a high power-rate performance during the charge and discharge process of the battery.

Original language	English
Pages (from-to)	827-831
Number of pages	5
Journal	Electrochimica Acta
Volume	50
Issue number	2-3 SPEC. ISS.
DOIs	https://doi.org/10.1016/j.electacta.2004.02.052
Publication status	Published - 2004 Nov 30

Keywords

Cathode materials
Lithium secondary batteries
Polymer batteries
Radical molecules

ASJC Scopus subject areas

Chemical Engineering(all)
Electrochemistry

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10.1016/j.electacta.2004.02.052

Cite this

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title = "Organic radical battery: Nitroxide polymers as a cathode-active material",

abstract = "Purely organic-derived nitroxide radicals, including their polymer derivative, poly(2,2,6,6-tetramethylpiperidinyloxy methacrylate) (PTMA), were characterized as a new class of cathode-active materials for lithium batteries. PTMA was stable at ambient conditions, had a tunable solubility and processability, and could undergo thermal runaway without any odor and ash. The nitroxide radicals displayed a reversible and very rapid redox to form their oxoammonium salts, which enabled a high power-rate performance during the charge and discharge process of the battery.",

keywords = "Cathode materials, Lithium secondary batteries, Polymer batteries, Radical molecules",

author = "Hiroyuki Nishide and Shigeyuki Iwasa and Pu, {Yong Jin} and Takeo Suga and Kentaro Nakahara and Masaharu Satoh",

note = "Funding Information: This work was partially supported by the NEDO Project on “High Power Density Radical Battery for Data-Backup”, and 21COE “Practical Nano-Chemistry” from MEXT, Japan. ",

year = "2004",

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doi = "10.1016/j.electacta.2004.02.052",

language = "English",

volume = "50",

pages = "827--831",

journal = "Electrochimica Acta",

issn = "0013-4686",

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TY - JOUR

T1 - Organic radical battery

T2 - Nitroxide polymers as a cathode-active material

AU - Nishide, Hiroyuki

AU - Iwasa, Shigeyuki

AU - Pu, Yong Jin

AU - Suga, Takeo

AU - Nakahara, Kentaro

AU - Satoh, Masaharu

N1 - Funding Information: This work was partially supported by the NEDO Project on “High Power Density Radical Battery for Data-Backup”, and 21COE “Practical Nano-Chemistry” from MEXT, Japan.

PY - 2004/11/30

Y1 - 2004/11/30

N2 - Purely organic-derived nitroxide radicals, including their polymer derivative, poly(2,2,6,6-tetramethylpiperidinyloxy methacrylate) (PTMA), were characterized as a new class of cathode-active materials for lithium batteries. PTMA was stable at ambient conditions, had a tunable solubility and processability, and could undergo thermal runaway without any odor and ash. The nitroxide radicals displayed a reversible and very rapid redox to form their oxoammonium salts, which enabled a high power-rate performance during the charge and discharge process of the battery.

AB - Purely organic-derived nitroxide radicals, including their polymer derivative, poly(2,2,6,6-tetramethylpiperidinyloxy methacrylate) (PTMA), were characterized as a new class of cathode-active materials for lithium batteries. PTMA was stable at ambient conditions, had a tunable solubility and processability, and could undergo thermal runaway without any odor and ash. The nitroxide radicals displayed a reversible and very rapid redox to form their oxoammonium salts, which enabled a high power-rate performance during the charge and discharge process of the battery.

KW - Cathode materials

KW - Lithium secondary batteries

KW - Polymer batteries

KW - Radical molecules

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JF - Electrochimica Acta

SN - 0013-4686

IS - 2-3 SPEC. ISS.

ER -

Organic radical battery: Nitroxide polymers as a cathode-active material

Abstract

Keywords

ASJC Scopus subject areas

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