Origin of the semiconducting-to-superconducting transition of La2-xCa1+xCu2O6 under high-oxygen-pressure annealing

H. Shibata, Azusa Matsuda, K. Kinoshita, T. Watanabe, T. Yamada

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The Madelung energy of La2-xCa1+xCu2O6 system, whose properties change from semiconductor to superconductor under high-oxygen-pressure annealing, is calculated. We find the increase in VA, the difference in Madelung site potential between the apex and the CuO2 planes oxygen, promotes the superconducting transition in this system. Slight intercalation of oxygen between two CuO2 planes is found to be of primary importance in determining VA.

Original languageEnglish
Pages (from-to)12315-12317
Number of pages3
JournalPhysical Review B
Volume49
Issue number17
DOIs
Publication statusPublished - 1994
Externally publishedYes

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high pressure oxygen
Annealing
Oxygen
annealing
oxygen
intercalation
apexes
Intercalation
Superconducting materials
Semiconductor materials
energy

ASJC Scopus subject areas

  • Condensed Matter Physics

Cite this

Origin of the semiconducting-to-superconducting transition of La2-xCa1+xCu2O6 under high-oxygen-pressure annealing. / Shibata, H.; Matsuda, Azusa; Kinoshita, K.; Watanabe, T.; Yamada, T.

In: Physical Review B, Vol. 49, No. 17, 1994, p. 12315-12317.

Research output: Contribution to journalArticle

Shibata, H. ; Matsuda, Azusa ; Kinoshita, K. ; Watanabe, T. ; Yamada, T. / Origin of the semiconducting-to-superconducting transition of La2-xCa1+xCu2O6 under high-oxygen-pressure annealing. In: Physical Review B. 1994 ; Vol. 49, No. 17. pp. 12315-12317.
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