Oxidation of adsorbed CO on Pt(111) in CO-saturated perchloric acid aqueous solutions

Simultaneous in situ time-resolved reflectance spectroscopy and second harmonic generation studies

Iosif Fromondi, Daniel Alberto Scherson

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Simultaneous normalized differential reflectance spectroscopy (ΔR/R) and second harmonic generation (SHG) has been employed to follow, independently, OH and adsorbed CO (COads) on a single Pt(111) microfacet in CO-saturated aqueous perchloric acidic solutions during voltammetric cycles, leading to the oxidation of COads and subsequent readsorption of CO on the surface. The results obtained are consistent with the disruption of the √19 × √19R19.1° phase just prior to the oxidation of adsorbed CO.

Original languageEnglish
Pages (from-to)20749-20751
Number of pages3
JournalJournal of Physical Chemistry B
Volume110
Issue number42
DOIs
Publication statusPublished - 2006 Oct 26
Externally publishedYes

Fingerprint

perchloric acid
Carbon Monoxide
Harmonic generation
Spectrum Analysis
harmonic generations
Spectroscopy
aqueous solutions
reflectance
Oxidation
oxidation
Acids
spectroscopy
cycles
Perchloric Acid

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

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abstract = "Simultaneous normalized differential reflectance spectroscopy (ΔR/R) and second harmonic generation (SHG) has been employed to follow, independently, OH and adsorbed CO (COads) on a single Pt(111) microfacet in CO-saturated aqueous perchloric acidic solutions during voltammetric cycles, leading to the oxidation of COads and subsequent readsorption of CO on the surface. The results obtained are consistent with the disruption of the √19 × √19R19.1° phase just prior to the oxidation of adsorbed CO.",
author = "Iosif Fromondi and Scherson, {Daniel Alberto}",
year = "2006",
month = "10",
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doi = "10.1021/jp0653095",
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T1 - Oxidation of adsorbed CO on Pt(111) in CO-saturated perchloric acid aqueous solutions

T2 - Simultaneous in situ time-resolved reflectance spectroscopy and second harmonic generation studies

AU - Fromondi, Iosif

AU - Scherson, Daniel Alberto

PY - 2006/10/26

Y1 - 2006/10/26

N2 - Simultaneous normalized differential reflectance spectroscopy (ΔR/R) and second harmonic generation (SHG) has been employed to follow, independently, OH and adsorbed CO (COads) on a single Pt(111) microfacet in CO-saturated aqueous perchloric acidic solutions during voltammetric cycles, leading to the oxidation of COads and subsequent readsorption of CO on the surface. The results obtained are consistent with the disruption of the √19 × √19R19.1° phase just prior to the oxidation of adsorbed CO.

AB - Simultaneous normalized differential reflectance spectroscopy (ΔR/R) and second harmonic generation (SHG) has been employed to follow, independently, OH and adsorbed CO (COads) on a single Pt(111) microfacet in CO-saturated aqueous perchloric acidic solutions during voltammetric cycles, leading to the oxidation of COads and subsequent readsorption of CO on the surface. The results obtained are consistent with the disruption of the √19 × √19R19.1° phase just prior to the oxidation of adsorbed CO.

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SN - 1520-6106

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