Oxidative polymerization of 2,6-dimethylphenol catalysed by insoluble polymer copper complexes

Hiroyuki Nishide, Y. Suzuki, E. Tsuchida

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Catalysis by insoluble polymerCu complexes was studied for the oxidative polymerization of 2,6-dimethylphenol. The polymerization was heterogeneously catalysed by the insoluble complex. The catalyst was readily recovered by filtration and could be re-used. Compared with the homogeneous system, the catalytic activity and the molecular weight of the produced polymer were lower for the insoluble polymerCu complex because of steric hindrance, low flexibility of the ligand part and low concentration of the effective copper ion.

Original languageEnglish
Pages (from-to)573-577
Number of pages5
JournalEuropean Polymer Journal
Volume17
Issue number5
DOIs
Publication statusPublished - 1981

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics

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