Oxovanadium(III-V) mononuclear complexes and their linear assemblies bearing tetradentate Schiff base ligands: Structure and reactivity as multielectron redox catalysts

Eishun Tsuchida; Kenichi Oyaizu

doi:10.1016/S0010-8545(02)00251-5

Oxovanadium(III-V) mononuclear complexes and their linear assemblies bearing tetradentate Schiff base ligands: Structure and reactivity as multielectron redox catalysts

Eishun Tsuchida^*, Kenichi Oyaizu

^*Corresponding author for this work

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

107 Citations (Scopus)

Abstract

This review summarizes the recent advances in the chemistry of oxovanadium(III-V) mononuclear complexes and their linear assemblies bearing tetradentate Schiff base ligands. Structural parameters of the oxovanadium assemblies are compiled, which reveal the preference of specific coordination geometries around vanadium atoms according to the valence state. Emphasis is placed on the catalysis of multielectron redox reactions by oxovanadium(IV) complexes which disproportionate to vanadium(III) and oxovanadium(V) complexes under suitable conditions. Their biological implications and synthetic applications are described.

Original language	English
Pages (from-to)	213-228
Number of pages	16
Journal	Coordination Chemistry Reviews
Volume	237
Issue number	1-2
DOIs	https://doi.org/10.1016/S0010-8545(02)00251-5
Publication status	Published - 2003 Feb

Keywords

Catalysis
Crystal structures
Oxovanadium complexes
Redox reaction
Schiff base ligands

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0010-8545(02)00251-5

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title = "Oxovanadium(III-V) mononuclear complexes and their linear assemblies bearing tetradentate Schiff base ligands: Structure and reactivity as multielectron redox catalysts",

abstract = "This review summarizes the recent advances in the chemistry of oxovanadium(III-V) mononuclear complexes and their linear assemblies bearing tetradentate Schiff base ligands. Structural parameters of the oxovanadium assemblies are compiled, which reveal the preference of specific coordination geometries around vanadium atoms according to the valence state. Emphasis is placed on the catalysis of multielectron redox reactions by oxovanadium(IV) complexes which disproportionate to vanadium(III) and oxovanadium(V) complexes under suitable conditions. Their biological implications and synthetic applications are described.",

keywords = "Catalysis, Crystal structures, Oxovanadium complexes, Redox reaction, Schiff base ligands",

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note = "Funding Information: Financial support by a Grant-in-Aid for Scientific Research (No. 14703029) from the Ministry of Education, Science, Sports, and Culture in Japan, and Health Science Research Grants (Artificial Blood Project) from the Ministry of Health, Labor and Welfare, Japan is acknowledged.",

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T2 - Structure and reactivity as multielectron redox catalysts

AU - Tsuchida, Eishun

AU - Oyaizu, Kenichi

N1 - Funding Information: Financial support by a Grant-in-Aid for Scientific Research (No. 14703029) from the Ministry of Education, Science, Sports, and Culture in Japan, and Health Science Research Grants (Artificial Blood Project) from the Ministry of Health, Labor and Welfare, Japan is acknowledged.

PY - 2003/2

Y1 - 2003/2

N2 - This review summarizes the recent advances in the chemistry of oxovanadium(III-V) mononuclear complexes and their linear assemblies bearing tetradentate Schiff base ligands. Structural parameters of the oxovanadium assemblies are compiled, which reveal the preference of specific coordination geometries around vanadium atoms according to the valence state. Emphasis is placed on the catalysis of multielectron redox reactions by oxovanadium(IV) complexes which disproportionate to vanadium(III) and oxovanadium(V) complexes under suitable conditions. Their biological implications and synthetic applications are described.

AB - This review summarizes the recent advances in the chemistry of oxovanadium(III-V) mononuclear complexes and their linear assemblies bearing tetradentate Schiff base ligands. Structural parameters of the oxovanadium assemblies are compiled, which reveal the preference of specific coordination geometries around vanadium atoms according to the valence state. Emphasis is placed on the catalysis of multielectron redox reactions by oxovanadium(IV) complexes which disproportionate to vanadium(III) and oxovanadium(V) complexes under suitable conditions. Their biological implications and synthetic applications are described.

KW - Catalysis

KW - Crystal structures

KW - Oxovanadium complexes

KW - Redox reaction

KW - Schiff base ligands

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JO - Coordination Chemistry Reviews

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Oxovanadium(III-V) mononuclear complexes and their linear assemblies bearing tetradentate Schiff base ligands: Structure and reactivity as multielectron redox catalysts

Abstract

Keywords

ASJC Scopus subject areas

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