Abstract
This review summarizes the recent advances in the chemistry of oxovanadium(III-V) mononuclear complexes and their linear assemblies bearing tetradentate Schiff base ligands. Structural parameters of the oxovanadium assemblies are compiled, which reveal the preference of specific coordination geometries around vanadium atoms according to the valence state. Emphasis is placed on the catalysis of multielectron redox reactions by oxovanadium(IV) complexes which disproportionate to vanadium(III) and oxovanadium(V) complexes under suitable conditions. Their biological implications and synthetic applications are described.
| Original language | English |
|---|---|
| Pages (from-to) | 213-228 |
| Number of pages | 16 |
| Journal | Coordination Chemistry Reviews |
| Volume | 237 |
| Issue number | 1-2 |
| DOIs | |
| Publication status | Published - 2003 Feb |
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Keywords
- Catalysis
- Crystal structures
- Oxovanadium complexes
- Redox reaction
- Schiff base ligands
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
Cite this
Oxovanadium(III-V) mononuclear complexes and their linear assemblies bearing tetradentate Schiff base ligands : Structure and reactivity as multielectron redox catalysts. / Tsuchida, Eishun; Oyaizu, Kenichi.
In: Coordination Chemistry Reviews, Vol. 237, No. 1-2, 02.2003, p. 213-228.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Oxovanadium(III-V) mononuclear complexes and their linear assemblies bearing tetradentate Schiff base ligands
T2 - Structure and reactivity as multielectron redox catalysts
AU - Tsuchida, Eishun
AU - Oyaizu, Kenichi
PY - 2003/2
Y1 - 2003/2
N2 - This review summarizes the recent advances in the chemistry of oxovanadium(III-V) mononuclear complexes and their linear assemblies bearing tetradentate Schiff base ligands. Structural parameters of the oxovanadium assemblies are compiled, which reveal the preference of specific coordination geometries around vanadium atoms according to the valence state. Emphasis is placed on the catalysis of multielectron redox reactions by oxovanadium(IV) complexes which disproportionate to vanadium(III) and oxovanadium(V) complexes under suitable conditions. Their biological implications and synthetic applications are described.
AB - This review summarizes the recent advances in the chemistry of oxovanadium(III-V) mononuclear complexes and their linear assemblies bearing tetradentate Schiff base ligands. Structural parameters of the oxovanadium assemblies are compiled, which reveal the preference of specific coordination geometries around vanadium atoms according to the valence state. Emphasis is placed on the catalysis of multielectron redox reactions by oxovanadium(IV) complexes which disproportionate to vanadium(III) and oxovanadium(V) complexes under suitable conditions. Their biological implications and synthetic applications are described.
KW - Catalysis
KW - Crystal structures
KW - Oxovanadium complexes
KW - Redox reaction
KW - Schiff base ligands
UR - http://www.scopus.com/inward/record.url?scp=0037295709&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0037295709&partnerID=8YFLogxK
U2 - 10.1016/S0010-8545(02)00251-5
DO - 10.1016/S0010-8545(02)00251-5
M3 - Article
AN - SCOPUS:0037295709
VL - 237
SP - 213
EP - 228
JO - Coordination Chemistry Reviews
JF - Coordination Chemistry Reviews
SN - 0010-8545
IS - 1-2
ER -