Oxovanadium(III-V) mononuclear complexes and their linear assemblies bearing tetradentate Schiff base ligands: Structure and reactivity as multielectron redox catalysts

Eishun Tsuchida, Kenichi Oyaizu

    Research output: Contribution to journalArticle

    99 Citations (Scopus)

    Abstract

    This review summarizes the recent advances in the chemistry of oxovanadium(III-V) mononuclear complexes and their linear assemblies bearing tetradentate Schiff base ligands. Structural parameters of the oxovanadium assemblies are compiled, which reveal the preference of specific coordination geometries around vanadium atoms according to the valence state. Emphasis is placed on the catalysis of multielectron redox reactions by oxovanadium(IV) complexes which disproportionate to vanadium(III) and oxovanadium(V) complexes under suitable conditions. Their biological implications and synthetic applications are described.

    Original languageEnglish
    Pages (from-to)213-228
    Number of pages16
    JournalCoordination Chemistry Reviews
    Volume237
    Issue number1-2
    DOIs
    Publication statusPublished - 2003 Feb

    Fingerprint

    Bearings (structural)
    Vanadium
    Schiff Bases
    vanadium
    assemblies
    imines
    reactivity
    Ligands
    catalysts
    ligands
    Catalysts
    Redox reactions
    Catalysis
    catalysis
    chemistry
    valence
    Atoms
    Geometry
    geometry
    atoms

    Keywords

    • Catalysis
    • Crystal structures
    • Oxovanadium complexes
    • Redox reaction
    • Schiff base ligands

    ASJC Scopus subject areas

    • Physical and Theoretical Chemistry

    Cite this

    @article{060d12826cf34e4c9a0f57ef54f325ff,
    title = "Oxovanadium(III-V) mononuclear complexes and their linear assemblies bearing tetradentate Schiff base ligands: Structure and reactivity as multielectron redox catalysts",
    abstract = "This review summarizes the recent advances in the chemistry of oxovanadium(III-V) mononuclear complexes and their linear assemblies bearing tetradentate Schiff base ligands. Structural parameters of the oxovanadium assemblies are compiled, which reveal the preference of specific coordination geometries around vanadium atoms according to the valence state. Emphasis is placed on the catalysis of multielectron redox reactions by oxovanadium(IV) complexes which disproportionate to vanadium(III) and oxovanadium(V) complexes under suitable conditions. Their biological implications and synthetic applications are described.",
    keywords = "Catalysis, Crystal structures, Oxovanadium complexes, Redox reaction, Schiff base ligands",
    author = "Eishun Tsuchida and Kenichi Oyaizu",
    year = "2003",
    month = "2",
    doi = "10.1016/S0010-8545(02)00251-5",
    language = "English",
    volume = "237",
    pages = "213--228",
    journal = "Coordination Chemistry Reviews",
    issn = "0010-8545",
    publisher = "Elsevier",
    number = "1-2",

    }

    TY - JOUR

    T1 - Oxovanadium(III-V) mononuclear complexes and their linear assemblies bearing tetradentate Schiff base ligands

    T2 - Structure and reactivity as multielectron redox catalysts

    AU - Tsuchida, Eishun

    AU - Oyaizu, Kenichi

    PY - 2003/2

    Y1 - 2003/2

    N2 - This review summarizes the recent advances in the chemistry of oxovanadium(III-V) mononuclear complexes and their linear assemblies bearing tetradentate Schiff base ligands. Structural parameters of the oxovanadium assemblies are compiled, which reveal the preference of specific coordination geometries around vanadium atoms according to the valence state. Emphasis is placed on the catalysis of multielectron redox reactions by oxovanadium(IV) complexes which disproportionate to vanadium(III) and oxovanadium(V) complexes under suitable conditions. Their biological implications and synthetic applications are described.

    AB - This review summarizes the recent advances in the chemistry of oxovanadium(III-V) mononuclear complexes and their linear assemblies bearing tetradentate Schiff base ligands. Structural parameters of the oxovanadium assemblies are compiled, which reveal the preference of specific coordination geometries around vanadium atoms according to the valence state. Emphasis is placed on the catalysis of multielectron redox reactions by oxovanadium(IV) complexes which disproportionate to vanadium(III) and oxovanadium(V) complexes under suitable conditions. Their biological implications and synthetic applications are described.

    KW - Catalysis

    KW - Crystal structures

    KW - Oxovanadium complexes

    KW - Redox reaction

    KW - Schiff base ligands

    UR - http://www.scopus.com/inward/record.url?scp=0037295709&partnerID=8YFLogxK

    UR - http://www.scopus.com/inward/citedby.url?scp=0037295709&partnerID=8YFLogxK

    U2 - 10.1016/S0010-8545(02)00251-5

    DO - 10.1016/S0010-8545(02)00251-5

    M3 - Article

    AN - SCOPUS:0037295709

    VL - 237

    SP - 213

    EP - 228

    JO - Coordination Chemistry Reviews

    JF - Coordination Chemistry Reviews

    SN - 0010-8545

    IS - 1-2

    ER -