Abstract
A tetradecyl-substituted diporphyrinatocopperiron complex was synthesized and solubilized in an aqueous medium with a surfactant. Both the oxygen- and carbon monoxide-binding rate constants decreased due to the steric hindrance of the porphyrinatocopper cap, which brought about a reduced gas-binding affinity in comparison with other synthetic porphyrinatoiron complexes.
| Original language | English |
|---|---|
| Pages (from-to) | 2963-2967 |
| Number of pages | 5 |
| Journal | Journal of the Chemical Society, Dalton Transactions |
| Issue number | 12 |
| DOIs | |
| Publication status | Published - 1987 |
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ASJC Scopus subject areas
- Chemistry(all)
Cite this
Oxygen- and carbon monoxide-binding to a lipophilic diporphyrinatocopperiron complex solubilized in an aqueous medium with a micelle. / Nishide, Hiroyuki; Hashimoto, Yukio; Maeda, Hiromi; Tsuchida, Eishun.
In: Journal of the Chemical Society, Dalton Transactions, No. 12, 1987, p. 2963-2967.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Oxygen- and carbon monoxide-binding to a lipophilic diporphyrinatocopperiron complex solubilized in an aqueous medium with a micelle
AU - Nishide, Hiroyuki
AU - Hashimoto, Yukio
AU - Maeda, Hiromi
AU - Tsuchida, Eishun
PY - 1987
Y1 - 1987
N2 - A tetradecyl-substituted diporphyrinatocopperiron complex was synthesized and solubilized in an aqueous medium with a surfactant. Both the oxygen- and carbon monoxide-binding rate constants decreased due to the steric hindrance of the porphyrinatocopper cap, which brought about a reduced gas-binding affinity in comparison with other synthetic porphyrinatoiron complexes.
AB - A tetradecyl-substituted diporphyrinatocopperiron complex was synthesized and solubilized in an aqueous medium with a surfactant. Both the oxygen- and carbon monoxide-binding rate constants decreased due to the steric hindrance of the porphyrinatocopper cap, which brought about a reduced gas-binding affinity in comparison with other synthetic porphyrinatoiron complexes.
UR - http://www.scopus.com/inward/record.url?scp=0041799386&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0041799386&partnerID=8YFLogxK
U2 - 10.1039/DT9870002963
DO - 10.1039/DT9870002963
M3 - Article
AN - SCOPUS:0041799386
SP - 2963
EP - 2967
JO - Dalton Transactions
JF - Dalton Transactions
SN - 1472-7773
IS - 12
ER -