Abstract
A tetradecyl-substituted diporphyrinatocopperiron complex was synthesized and solubilized in an aqueous medium with a surfactant. Both the oxygen- and carbon monoxide-binding rate constants decreased due to the steric hindrance of the porphyrinatocopper cap, which brought about a reduced gas-binding affinity in comparison with other synthetic porphyrinatoiron complexes.
Original language | English |
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Pages (from-to) | 2963-2967 |
Number of pages | 5 |
Journal | Journal of the Chemical Society, Dalton Transactions |
Issue number | 12 |
DOIs | |
Publication status | Published - 1987 |
ASJC Scopus subject areas
- Chemistry(all)