Abstract
A tetradecyl-substituted diporphyrinatocopperiron complex was synthesized and solubilized in an aqueous medium with a surfactant. Both the oxygen- and carbon monoxide-binding rate constants decreased due to the steric hindrance of the porphyrinatocopper cap, which brought about a reduced gas-binding affinity in comparison with other synthetic porphyrinatoiron complexes.
| Original language | English |
|---|---|
| Pages (from-to) | 2963-2967 |
| Number of pages | 5 |
| Journal | Journal of the Chemical Society, Dalton Transactions |
| Issue number | 12 |
| DOIs | |
| Publication status | Published - 1987 |
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ASJC Scopus subject areas
- Chemistry(all)
Cite this
Nishide, H., Hashimoto, Y., Maeda, H., & Tsuchida, E. (1987). Oxygen- and carbon monoxide-binding to a lipophilic diporphyrinatocopperiron complex solubilized in an aqueous medium with a micelle. Journal of the Chemical Society, Dalton Transactions, (12), 2963-2967. https://doi.org/10.1039/DT9870002963