Oxygen- and carbon monoxide-binding to a lipophilic diporphyrinatocopperiron complex solubilized in an aqueous medium with a micelle

Hiroyuki Nishide; Yukio Hashimoto; Hiromi Maeda; Eishun Tsuchida

doi:10.1039/DT9870002963

Oxygen- and carbon monoxide-binding to a lipophilic diporphyrinatocopperiron complex solubilized in an aqueous medium with a micelle

Hiroyuki Nishide, Yukio Hashimoto, Hiromi Maeda, Eishun Tsuchida

Waseda Research Institute for Science and Engineering

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

A tetradecyl-substituted diporphyrinatocopperiron complex was synthesized and solubilized in an aqueous medium with a surfactant. Both the oxygen- and carbon monoxide-binding rate constants decreased due to the steric hindrance of the porphyrinatocopper cap, which brought about a reduced gas-binding affinity in comparison with other synthetic porphyrinatoiron complexes.

Original language	English
Pages (from-to)	2963-2967
Number of pages	5
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	12
DOIs	https://doi.org/10.1039/DT9870002963
Publication status	Published - 1987

ASJC Scopus subject areas

Chemistry(all)

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10.1039/DT9870002963

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abstract = "A tetradecyl-substituted diporphyrinatocopperiron complex was synthesized and solubilized in an aqueous medium with a surfactant. Both the oxygen- and carbon monoxide-binding rate constants decreased due to the steric hindrance of the porphyrinatocopper cap, which brought about a reduced gas-binding affinity in comparison with other synthetic porphyrinatoiron complexes.",

author = "Hiroyuki Nishide and Yukio Hashimoto and Hiromi Maeda and Eishun Tsuchida",

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AU - Hashimoto, Yukio

AU - Maeda, Hiromi

AU - Tsuchida, Eishun

PY - 1987

Y1 - 1987

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AB - A tetradecyl-substituted diporphyrinatocopperiron complex was synthesized and solubilized in an aqueous medium with a surfactant. Both the oxygen- and carbon monoxide-binding rate constants decreased due to the steric hindrance of the porphyrinatocopper cap, which brought about a reduced gas-binding affinity in comparison with other synthetic porphyrinatoiron complexes.

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