Oxygen- and carbon monoxide-binding to a lipophilic diporphyrinatocopperiron complex solubilized in an aqueous medium with a micelle

Hiroyuki Nishide, Yukio Hashimoto, Hiromi Maeda, Eishun Tsuchida

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Abstract

A tetradecyl-substituted diporphyrinatocopperiron complex was synthesized and solubilized in an aqueous medium with a surfactant. Both the oxygen- and carbon monoxide-binding rate constants decreased due to the steric hindrance of the porphyrinatocopper cap, which brought about a reduced gas-binding affinity in comparison with other synthetic porphyrinatoiron complexes.

Original languageEnglish
Pages (from-to)2963-2967
Number of pages5
JournalJournal of the Chemical Society, Dalton Transactions
Issue number12
DOIs
Publication statusPublished - 1987

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ASJC Scopus subject areas

  • Chemistry(all)

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