Oxygen evolution reaction on transition metal borides

Tetsuya Osaka, Hiroyuki Ishibashi, Tetsuo Endo, Tadashi Yoshida

Research output: Contribution to journalArticle

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Abstract

The oxygen evolution reaction on the transition metal borides (mainly CoxB and NixB) was investigated with various composition ratio of BMetal and sintering temperature. The activity of oxygen evolution reaction became maximum at the composition range of BCo = 1 3 and BNi ≥ 1 3, respectively. The sintering temperature also affected largely the activity of oxygen evolution reaction and the metal borides with the composition ratio BMetal = 1 3 gave the highest activity at the sintering temperature lower than 300°C for nickel borides and 400 ∼ 500°C for cobalt borides. The oxygen evolution reaction on iron boride and lanthanum hexaboride was also briefly discussed, and the order of the activity of oxygen evolution reaction was as follows: {A figure is presented} The Tafel slope of oxygen evolution reaction on metal borides was varied from ca. 40 mV for Ni (ca 70 mV for Co) to ca. 120 mV with the increase in the activity of oxygen evolution reaction. The oxide formation became easier with the increase in the activity of oxygen evolution reaction and the differential capacity of the oxide formation in the range more cathodic than the oxygen evolution increased with the decrease in the apparent activation energy of oxygen evolution reaction at 0.60 V (HgHgO).

Original languageEnglish
Pages (from-to)339-343
Number of pages5
JournalElectrochimica Acta
Volume26
Issue number3
DOIs
Publication statusPublished - 1981

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Boron Compounds
Borides
Transition metals
Oxygen
Sintering
Oxides
Metals
Chemical analysis
Lanthanum
Cobalt
Temperature
Iron

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Analytical Chemistry
  • Electrochemistry

Cite this

Oxygen evolution reaction on transition metal borides. / Osaka, Tetsuya; Ishibashi, Hiroyuki; Endo, Tetsuo; Yoshida, Tadashi.

In: Electrochimica Acta, Vol. 26, No. 3, 1981, p. 339-343.

Research output: Contribution to journalArticle

Osaka, Tetsuya ; Ishibashi, Hiroyuki ; Endo, Tetsuo ; Yoshida, Tadashi. / Oxygen evolution reaction on transition metal borides. In: Electrochimica Acta. 1981 ; Vol. 26, No. 3. pp. 339-343.
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AB - The oxygen evolution reaction on the transition metal borides (mainly CoxB and NixB) was investigated with various composition ratio of BMetal and sintering temperature. The activity of oxygen evolution reaction became maximum at the composition range of BCo = 1 3 and BNi ≥ 1 3, respectively. The sintering temperature also affected largely the activity of oxygen evolution reaction and the metal borides with the composition ratio BMetal = 1 3 gave the highest activity at the sintering temperature lower than 300°C for nickel borides and 400 ∼ 500°C for cobalt borides. The oxygen evolution reaction on iron boride and lanthanum hexaboride was also briefly discussed, and the order of the activity of oxygen evolution reaction was as follows: {A figure is presented} The Tafel slope of oxygen evolution reaction on metal borides was varied from ca. 40 mV for Ni (ca 70 mV for Co) to ca. 120 mV with the increase in the activity of oxygen evolution reaction. The oxide formation became easier with the increase in the activity of oxygen evolution reaction and the differential capacity of the oxide formation in the range more cathodic than the oxygen evolution increased with the decrease in the apparent activation energy of oxygen evolution reaction at 0.60 V (HgHgO).

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