Oxygen Redox Versus Oxygen Evolution in Aqueous Electrolytes: Critical Influence of Transition Metals

Hirohito Umeno, Kosuke Kawai, Daisuke Asakura, Masashi Okubo, Atsuo Yamada*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

Aqueous lithium-ion batteries are promising electrochemical energy storage devices owing to their sustainable nature, low cost, high level of safety, and environmental benignity. The recent development of a high-salt-concentration strategy for aqueous electrolytes, which significantly expands their electrochemical potential window, has created attractive opportunities to explore high-performance electrode materials for aqueous lithium-ion batteries. This study evaluates the compatibility of large-capacity oxygen-redox cathodes with hydrate-melt electrolytes. Using conventional oxygen-redox cathode materials (Li2RuO3, Li1.2Ni0.13Co0.13Mn0.54O2, and Li1.2Ni0.2Mn0.6O2), it is determined that avoiding the use of transition metals with high catalytic activity for the oxygen evolution reaction is the key to ensuring the stable progress of the oxygen redox reaction in concentrated aqueous electrolytes.

Original languageEnglish
Article number2104907
JournalAdvanced Science
Volume9
Issue number12
DOIs
Publication statusPublished - 2022 Apr 25
Externally publishedYes

Keywords

  • aqueous batteries
  • aqueous electrolyte
  • batteries
  • cathodes
  • oxygen evolution
  • oxygen redox

ASJC Scopus subject areas

  • Medicine (miscellaneous)
  • Chemical Engineering(all)
  • Materials Science(all)
  • Biochemistry, Genetics and Molecular Biology (miscellaneous)
  • Engineering(all)
  • Physics and Astronomy(all)

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