Oxygenation Behaviour of the Porphine-Porphinatoiron Complex

Shen Guo Wang, Hiroyuki Nishide, Eishun Tsuchida

Research output: Contribution to journalArticle

Abstract

Porphine-porphinatoiron (II) [1] was synthesized from 3, 8,13,18-tetramethyl-2,12-diethyl-porphine-7,17-diacetic acid. The complex with imidazole was in a 5-coordinate and high-spin form due to steric effect of the capped porphine. The oxygen adduct of [1] was formed below 0°C, and the life time of the oxygen adduct was longer than that of the corresponding porphinatoiron(II) under the same conditions.

Original languageEnglish
Pages (from-to)182-184
Number of pages3
JournalNippon Kagaku Kaishi / Chemical Society of Japan - Chemistry and Industrial Chemistry Journal
Volume1985
Issue number2
DOIs
Publication statusPublished - 1985

ASJC Scopus subject areas

  • Chemistry(all)

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