Oxygenation of a new bis-fenced porphyrinato iron without amide groups: 5,10,15,20-Tetrakis(2,6-bispivaloyloxyphenyl)porphyrinatoiron(II)

Teruyuki Komatsu, Etsuo Hasegawa, Hiroyuki Nishide, Eishun Tsuchida

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

A new porphyrinatoiron complex, 5,10,15,20-tetrakis(2,6- bispivaloyloxyphenyl)porphyrinatoriron(II), has been synthesized; axial-base ligation was sterically depressed by the four ester groups on each side of the porphyrin plane and a stable dioxygen adduct formed reversibly at 25°C in toluene.

Original languageEnglish
Pages (from-to)66-68
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number1
DOIs
Publication statusPublished - 1990

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Oxygenation
Porphyrins
Toluene
Amides
Ligation
Esters
Iron
Oxygen
porphyrinatoiron(II)

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

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abstract = "A new porphyrinatoiron complex, 5,10,15,20-tetrakis(2,6- bispivaloyloxyphenyl)porphyrinatoriron(II), has been synthesized; axial-base ligation was sterically depressed by the four ester groups on each side of the porphyrin plane and a stable dioxygen adduct formed reversibly at 25°C in toluene.",
author = "Teruyuki Komatsu and Etsuo Hasegawa and Hiroyuki Nishide and Eishun Tsuchida",
year = "1990",
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T2 - 5,10,15,20-Tetrakis(2,6-bispivaloyloxyphenyl)porphyrinatoiron(II)

AU - Komatsu, Teruyuki

AU - Hasegawa, Etsuo

AU - Nishide, Hiroyuki

AU - Tsuchida, Eishun

PY - 1990

Y1 - 1990

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AB - A new porphyrinatoiron complex, 5,10,15,20-tetrakis(2,6- bispivaloyloxyphenyl)porphyrinatoriron(II), has been synthesized; axial-base ligation was sterically depressed by the four ester groups on each side of the porphyrin plane and a stable dioxygen adduct formed reversibly at 25°C in toluene.

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