Palladium-catalyzed [3 + 2] cycloaddition reaction using 2-(sulfonylmethyl)- or 2-(cyanomethyl)allyl carbonate

Isao Shimizu, Yukihiro Ohashi, Jiro Tsuji

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    70 Citations (Scopus)

    Abstract

    Reaction of ethyl 2-(sulfonylmethyl)- or 2-(cyanomethyl)allyl carbonate with α,β-unsaturated esters or ketones in the presence of PD2(dba)3·.CHCl3-dppe catalyst gave highly functionalized cyclopentanes regio-selectively in good yields.

    Original languageEnglish
    Pages (from-to)5183-5186
    Number of pages4
    JournalTetrahedron Letters
    Volume25
    Issue number45
    DOIs
    Publication statusPublished - 1984

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    ASJC Scopus subject areas

    • Biochemistry
    • Organic Chemistry
    • Drug Discovery

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