Palladium-catalyzed allylation of ketones and aldehydes via allyl enol carbonates

Jiro Tsuji, Ichiro Minami, Isao Shimizu

    Research output: Contribution to journalArticle

    98 Citations (Scopus)

    Abstract

    Rearrangement of allyl enol carbonates, prepared from ketones or aldehydes by trapping their enolates with allyl chloroformate, to give α-allyl ketones or aldehydes regioselectivity is catalyzed by palladium-phosphine complexes under mild conditions.

    Original languageEnglish
    Pages (from-to)1793-1796
    Number of pages4
    JournalTetrahedron Letters
    Volume24
    Issue number17
    DOIs
    Publication statusPublished - 1983

    ASJC Scopus subject areas

    • Biochemistry
    • Organic Chemistry
    • Drug Discovery

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