@article{4fe0161f5cc34d6cac8800f85a1a9105,
title = "Palladium-Catalyzed Carbothiolation via Trapping of the σ-Alkyl Palladium Intermediate with RSTIPS",
abstract = "A palladium-catalyzed carbothiolation via the reaction of a σ-alkyl palladium intermediate with a TIPS thioether is described. It was found that the use of Cs2CO3, (IPr)Pd(allyl)Cl, and a TIPS thioether was key to obtaining alkyl aryl and dialkyl sulfides in high yield through the reaction of a σ-alkyl palladium intermediate. The developed reaction is applicable to a wide range of substrates and thiols.",
author = "Yosuke Hosoya and Ikumi Kobayashi and Kota Mizoguchi and Masahisa Nakada",
note = "Funding Information: We acknowledge supports of the Materials Characterization Central Laboratory, Waseda University, for characterization of new compounds. This work was financially supported in part by JSPS KAKENHI (Grant No. JP15H05841 in Middle Molecular Strategy) and a Waseda University Grant for Special Research Projects. Funding Information: We acknowledge supports of the Materials Characterization Central Laboratory, Waseda University, for characterization of new compounds. This work was financially supported in part by JSPS KAKENHI (Grant No. JP15H05841 in Middle Molecular Strategy) and a Waseda University Grant for Special Research Projects.",
year = "2019",
month = oct,
day = "18",
doi = "10.1021/acs.orglett.9b03046",
language = "English",
volume = "21",
pages = "8280--8284",
journal = "Organic Letters",
issn = "1523-7060",
publisher = "American Chemical Society",
number = "20",
}