Palladium-Catalyzed Decarbonylative Cross-Coupling of Azinecarboxylates with Arylboronic Acids

Kei Muto, Taito Hatakeyama, Kenichiro Itami, Junichiro Yamaguchi

Research output: Contribution to journalArticlepeer-review

32 Citations (Scopus)

Abstract

The first palladium-catalyzed decarbonylative coupling of phenyl 2-azinecarboxylates and arylboronic acids is presented. The key for the development of this decarbonylative coupling is the use of Pd/dcype as a catalyst. A wide range of 2-azinecarboxylates can undergo the present coupling reaction to afford 2-arylazines. By combination with previously reported nickel-catalyzed decarbonylative coupling, we achieved a chemoselective sequential decarbonylative coupling of pyridine dicarboxylate to synthesize 2,4-diarylpyridine.

Original languageEnglish
Pages (from-to)5106-5109
Number of pages4
JournalOrganic Letters
Volume18
Issue number19
DOIs
Publication statusPublished - 2016 Oct 7

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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