Palladium-catalyzed rearrangement of allylic esters of acetoacetic acid to give γ,δ-unsaturated methyl ketones

Isao Shimizu, Toshiro Yamada, Jiro Tsuji

    Research output: Contribution to journalArticle

    187 Citations (Scopus)

    Abstract

    Various allylic esters of acetoacetic acid undergo rearrangement to give γ,δ-unsaturated methyl ketones in high yields with elimination of carbon dioxide under mild conditions in the presence of catalytic amounts of Pd(OAc)2 and PPh3.

    Original languageEnglish
    Pages (from-to)3199-3202
    Number of pages4
    JournalTetrahedron Letters
    Volume21
    Issue number33
    DOIs
    Publication statusPublished - 1980

      Fingerprint

    ASJC Scopus subject areas

    • Biochemistry
    • Organic Chemistry
    • Drug Discovery

    Cite this