Palladium-catalyzed synthesis of α,β-unsaturated ketones from ketones via allyl enol carbonates

Isao Shimizu, Ichiro Minami, Jiro Tsuji

    Research output: Contribution to journalArticlepeer-review

    52 Citations (Scopus)

    Abstract

    Allyl enol carbonates, prepared by quenching ketone enolates with allyl chloroformate, are converted to α,β-unsaturated ketones with Pd(OAc)2-dppe catalyst in CH3CN.

    Original languageEnglish
    Pages (from-to)1797-1800
    Number of pages4
    JournalTetrahedron Letters
    Volume24
    Issue number17
    DOIs
    Publication statusPublished - 1983

    ASJC Scopus subject areas

    • Biochemistry
    • Organic Chemistry
    • Drug Discovery

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