Pd-Catalyzed Dearomative Allylation of Benzyl Phosphates

Masaaki Komatsuda, Kei Muto*, Junichiro Yamaguchi

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

19 Citations (Scopus)

Abstract

Dearomative C-C bond formation of benzyl phosphates has been developed. In the presence of a palladium/PAr3 catalyst, benzyl phosphates reacted with allyl borates to generate the allylated product in a dearomative fashion. The resulting dearomatized molecules were successfully derivatized by Simmons-Smith cyclopropanation and oxidation.

Original languageEnglish
Pages (from-to)4354-4357
Number of pages4
JournalOrganic Letters
Volume20
Issue number14
DOIs
Publication statusPublished - 2018 Jul 20

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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