Pd-Catalyzed Dearomative Three-Component Reaction of Bromoarenes with Diazo Compounds and Allylborates

Masaaki Komatsuda, Hiroki Kato, Kei Muto, Junichiro Yamaguchi

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

A catalytic dearomative three-component reaction of bromoarenes with TMS-diazomethane and allyl borate was developed. The key of this assembling reaction is the use of a diazo compound to generate a Pd-π-benzyl intermediate through a Pd-carbene species. This method allowed for a dearomative functionalization, using arenes as limiting reagents. Heteroaryl bromides were also applicable to give dearomatized structures under the reaction conditions.

Original languageEnglish
Pages (from-to)8991-8995
Number of pages5
JournalACS Catalysis
Volume9
Issue number10
DOIs
Publication statusPublished - 2019 Jan 1

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Keywords

  • (Hetero)arenes
  • Alicyclic compounds
  • Dearomatization
  • Diazo compounds
  • Palladium

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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