@article{0a9f2d1f44fa4eb0ade59b7541245b32,
title = "Pd-Catalyzed Denitrative Intramolecular C-H Arylation",
abstract = "A Pd-catalyzed intramolecular C-H arylation of nitroarenes has been developed. Nitroarenes bearing tethered aryl groups at the ortho-position can be readily prepared in one step from 2-halonitroarenes by a nucleophilic aromatic substitution (SNAr). Under Pd/BrettPhos catalysis, activations of the C-NO2 bond as well as the C-H bond on arenes generated the corresponding biaryl linkage in moderate to excellent yields.",
author = "Asahara, {Kitty K.} and Toshimasa Okita and Saito, {Ami N.} and Kei Muto and Yoshiaki Nakao and Junichiro Yamaguchi",
note = "Funding Information: This work was supported by JSPS KAKENHI grant no. JP19H02726, JP18H04272 (to J.Y.), JP15H05799 (to Y. N.), and JP19K15573 (to K.M.). Funding Information: This work was supported by JSPS KAKENHI grant no. JP19H02726, JP18H04272 (to J.Y.), JP15H05799 (to Y. N.), and JP19K15573 (to K.M.). We thank Myuto Kashihara (Kyoto University) for fruitful discussion and critical comments. The Materials Characterization Central Laboratory in Waseda University is acknowledged for HRMS measurement. Publisher Copyright: {\textcopyright} 2019 American Chemical Society.",
year = "2019",
month = jun,
day = "21",
doi = "10.1021/acs.orglett.9b01593",
language = "English",
volume = "21",
pages = "4721--4724",
journal = "Organic Letters",
issn = "1523-7060",
publisher = "American Chemical Society",
number = "12",
}