Performance evaluation of organoclays for the amoxicillin retention in a dynamic context

Régis Guégan, Lydie Le Forestier

Research output: Contribution to journalArticlepeer-review

Abstract

The hydraulic conductivity of diverse organoclays was determined through percolation experiments and compared to a raw Na-montmorillonite (Na-Mt). The incorporation of surfactants even at low content drastically changes the hydraulic conductivity with a large increase of about two order of magnitude in contrast to that of Na-Mt (10−12 m s−1). Batch kinetics and equilibrium adsorption experiments confirmed the proper affinity of organoclays to a zwitterion antibiotic: the amoxicillin (AMX) which was quickly adsorbed (at a time below 30 min) at large amounts (up to 1.4 × 10−3 mol g−1). However, in percolation conditions, the significant increase of the permeability led to a short interaction time between the organoclays and the pharmaceutical. In contrast to Na-Mt for which it took age to get only one drop of AMX, leachates, resulting of a percolation through organoclays, were collected for a time below 10 min, not enough sufficient to ensure a proper removal of an antibiotic with concentration reduced by 5–80% of the initial solution.

Original languageEnglish
Article number126859
JournalChemical Engineering Journal
Volume406
DOIs
Publication statusPublished - 2021 Feb 15

Keywords

  • Adsorption
  • Amoxicillin
  • Hydraulic conductivity
  • Organoclays
  • Percolation experiments

ASJC Scopus subject areas

  • Chemistry(all)
  • Environmental Chemistry
  • Chemical Engineering(all)
  • Industrial and Manufacturing Engineering

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